Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

被引：17
|
作者：
Huang, Jun [1 ]
Li, Linyong [1 ]
Chen, Haoguo [1 ]
Xiao, Tiebo [1 ]
He, Yuwei [1 ]
Zhou, Lei [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 04期
基金：
中国国家自然科学基金;
关键词：
ALPHA-DIAZOCARBONYL COMPOUNDS; C-H FUNCTIONALIZATION; DIAZO-COMPOUNDS; CARBENE INSERTION; ORGANIC-SYNTHESIS; TANDEM REACTION; BOND FORMATION; METAL CARBENE; TOSYLHYDRAZONES; CONSTRUCTION;
D O I：
10.1039/c6qo00813e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for gem-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.
引用
收藏
页码：529 / 533
页数：5
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