Electrospun Gelatin Membrane Cross-Linked by a Bis(diarylcarbene) for Oil/Water Separation: A New Strategy To Prepare Porous Organic Polymers

被引:10
|
作者
Yu, Xi [1 ]
Yang, Pengfei [1 ]
Moloney, Mark G. [2 ]
Wang, Liang [3 ]
Xu, Jinku [1 ]
Wang, Yongqing [1 ]
Liu, Lian [1 ]
Pan, Yunlin [1 ]
机构
[1] Qilu Univ Technol, Shandong Acad Sci, Sch Chem & Pharmaceut Engn, Jinan 250353, Shandong, Peoples R China
[2] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England
[3] Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Qingdao 266109, Peoples R China
来源
ACS OMEGA | 2018年 / 3卷 / 04期
基金
中国国家自然科学基金;
关键词
SURFACE HYDROPHOBIC MODIFICATION; OIL-SPILL; INTRINSIC MICROPOROSITY; FUNCTIONALIZATION; POLYMERIZATION; FRAMEWORKS; SPONGE; ABSORPTION; LINKING; ROBUST;
D O I
10.1021/acsomega.8b00162
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Porous organic polymers (POPs) as absorbing materials have attracted increasing attention. Here, we report a new approach to prepare these polymers for selective oil absorption from oil/water mixtures. Perfluoroalkylbis(diaryldiazomethane) was synthesized and used to modify the surface of an electrospun gelatin membrane by a carbene insertion reaction, not only to immobilize the porous network morphology by cross-linking but also to introduce perfluoroalkyl groups for oil/water separation. The membrane was characterized to show its surface and bulk properties, as well as its performance for absorption capacity, selectivity, and renewability. This approach offers a new horizon in the preparation of POPs for oil/water separation.
引用
收藏
页码:3928 / 3935
页数:8
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