Elaboration of Thermoresponsive Supramolecular Diblock Copolymers in Water from Complementary CBPQT4+ and TTF End-Functionalized Polymers

被引：14

作者：

Sambe, Lena ^{[1
]}

Stoffelbach, Francois ^{[2
]}

Poltorak, Katarzyna ^{[2
]}

Lyskawa, Joel ^{[1
]}

Malfait, Aurelie ^{[1
]}

Bria, Marc ^{[1
]}

Cooke, Graeme ^{[3
]}

Woisel, Patrice ^{[1
]}

机构：

[1] Univ Lille Nord France, UMET UMR8207, ENSCL, F-59655 Villeneuve Dascq, France

[2] Univ Paris 06, CNRS, UMR 7610, Lab Chim Polymeres, F-94200 Ivry, France

[3] Univ Glasgow, Sch Chem, Glasgow Ctr Phys Organ Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2014年 / 35卷 / 04期

关键词：

block copolymer; host-guest interaction; thermoresponsive; BLOCK-COPOLYMERS; CLICK CHEMISTRY; POLY(N-ISOPROPYLACRYLAMIDE); TETRATHIAFULVALENE; COMPLEXATION; CYCLOBIS(PARAQUAT-PARA-PHENYLENE); CYCLOBIS(PARAQUAT-P-PHENYLENE); DERIVATIVES; SURFACE;

D O I：

10.1002/marc.201300729

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A well-defined poly(N-isopropyl acrylamide) 1 incorporating at one termini a cyclobis(paraquat-p-phenylene) (CBPQT(4+)) recognition unit is prepared via a RAFT polymerization followed by a copper-catalyzed azide-alkyne cycloaddition (CuAAC). H-1 NMR (1D, DOSY), UV-vis and ITC experiments reveal that polymer 1 is able of forming effective host-guest complexes with tetrathiafulvalene (TTF) end-functionalized polymers in water, thereby leading to the formation of non-covalently-linked double-hydrophilic block copolymers. The effect of the temperature on both the LCST phase transition of 1 and its complexes and on CBPQT(4+)/TTF host-guest interactions is investigated.

引用

页码：498 / 504

页数：7

共 5 条

[1] Thermoresponsive catechol end-functionalized polymers/CBPQT4+, 4Cl- supramolecular assembly
Defrancois, Sarah
Bouad, Vincent
Woisel, Patrice
Lyskawa, Joel
[J]. JOURNAL OF POLYMER SCIENCE, 2023, 61 (07) : 534 - 541
[2] Complexation of thermoresponsive dialkoxynaphthalene end-functionalized poly(oligoethylene glycol acrylate)s with CBPQT4+ in water
Yeniad, Bahar
Ryskulova, Kanykei
Fournier, David
Lyskawa, Joel
Cooke, Graeme
Woisel, Patrice
Hoogenboom, Richard
[J]. POLYMER CHEMISTRY, 2016, 7 (22) : 3681 - 3690
[3] Dynamic Covalent Diblock Copolymers Prepared from RAFT Generated Aldehyde and Alkoxyamine End-Functionalized Polymers
Jackson, Alexander W.
Fulton, David A.
[J]. MACROMOLECULES, 2010, 43 (02) : 1069 - 1075
[4] End-Functionalized Polymers and Junction-Functionalized Diblock Copolymers Via RAFT Chain Extension with Maleimido Monomers
Henry, Scott M.
Convertine, Anthony J.
Benoit, Danielle S. W.
Hoffman, Allan S.
Stayton, Patrick S.
[J]. BIOCONJUGATE CHEMISTRY, 2009, 20 (06) : 1122 - 1128
[5] Thermoresponsive behavior of micellar aggregates from end-functionalized PnBA-b-PNIPAM-COOH block copolymers and their complexes with lysozyme
Papagiannopoulos, Aristeidis
Meristoudi, Anastasia
Pispas, Stergios
Keiderling, Uwe
[J]. SOFT MATTER, 2016, 12 (31) : 6547 - 6556

← 1 →