Direct oxidation of isobutane to methacrolein over V-MCM-41 catalysts

被引：28
|
作者：
Jia, MJ
Valenzuela, RX
Amorós, P
Beltrán-Porter, D
El-Haskouri, J
Marcos, MD
Corberán, VC
机构：
[1] CSIC, Inst Catalysis & Petroleumchem, E-28049 Madrid, Spain
[2] Univ Valencia, ICMUV, Inst Ciencia Mat, E-46071 Valencia, Spain
[3] Univ Politecn Valencia, Dept Chem, E-46071 Valencia, Spain
来源：
CATALYSIS TODAY | 2004年 / 91-2卷
关键词：
oxidative dehydrogenation; isobutane; methacrolein from isobutane; V-MCM-41; catalysts;
D O I：
10.1016/j.cattod.2004.03.007
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
High vanadium content mesoporous vanado-silicates with MCM-41-like structure, obtained by the atrane route, catalyse the direct oxidation of isobutane to methacrolein with 30% selectivity, and a total dehydrogenation (olefin plus methacrolein) selectivity up to 74%. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：43 / 47
页数：5
相关论文
共 50 条
  • [1] Selective oxidation of ethanol on V-MCM-41 catalysts
    Canepa, Analia L.
    Vaschetti, Virginia M.
    Pajaro, Karen C.
    Eimer, Griselda A.
    Casuscelli, Sandra G.
    Cortes Corberan, Vicente
    CATALYSIS TODAY, 2020, 356 : 464 - 470
  • [2] Synthesis of V-MCM-41 Catalysts and Their Application in CO2-Assisted Isobutane Dehydrogenation
    Wang, Xiaosheng
    Ji, Kehong
    Zhou, Guanglin
    Li, Qin
    Zhou, Hongjun
    Xu, Chunming
    CHEMICAL ENGINEERING & TECHNOLOGY, 2018, 41 (03) : 563 - 572
  • [3] Oxidation of organosulfur compounds with tert-butyl hydroperoxide over Ti and V-MCM-41 catalysts
    Fabis, Grazyna
    Sarbak, Zenon
    PRZEMYSL CHEMICZNY, 2009, 88 (01): : 83 - 86
  • [4] Gas phase methanol oxidation on V-MCM-41
    Lim, SY
    Haller, GL
    APPLIED CATALYSIS A-GENERAL, 1999, 188 (1-2) : 277 - 286
  • [5] Phosphorous modified V-MCM-41 catalysts for propane dehydrogenation
    Wang, Xiao-Sheng
    Yang, Tao
    Li, Qin
    Liu, Yu-Xiang
    Ding, Yong-Chuan
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2022, 50 (02): : 227 - 236
  • [6] V-MCM-41 for selective oxidation of propane to propene and acrolein
    Zhang, QH
    Wang, Y
    Ohishi, Y
    Shishido, T
    Takehira, K
    CHEMISTRY LETTERS, 2001, (03) : 194 - 195
  • [7] Ethylene and acetaldehyde production by selective oxidation of ethanol using mesoporous V-MCM-41 catalysts
    Gucbilmez, Yesim
    Dogu, Timur
    Balci, Suna
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (10) : 3496 - 3502
  • [8] Radius of curvature effect of V-MCM-41 probed by methanol oxidation
    Yang, YH
    Du, GA
    Lim, SY
    Haller, GL
    JOURNAL OF CATALYSIS, 2005, 234 (02) : 318 - 327
  • [9] Radius of Curvature Effect on the Selective Oxidation of Cyclohexene Over Highly Ordered V-MCM-41
    Qinghu Tang
    Chuan Wang
    Shuangquan Hu
    Hui Sun
    Yuan Chen
    Gary L. Haller
    Yanhui Yang
    Catalysis Letters, 2007, 117 : 25 - 33
  • [10] Radius of curvature effect on the selective oxidation of cyclohexene over highly ordered V-MCM-41
    Tang, Qinghu
    Wang, Chuan
    Hu, Shuangquan
    Hui, Sun
    Yuan, Chen
    Haller, Gary L.
    Yang, Yanhui
    CATALYSIS LETTERS, 2007, 117 (1-2) : 25 - 33
12345