Toward Practical Application Of H2 Generation From Ammonia Decomposition Guided by Rational Catalyst Design

被引：96

作者：

Garcia-Bordeje, Enrique ^{[1
]}

Armenise, Sabino ^{[1
]}

Roldan, Laura ^{[1
]}

机构：

[1] Inst Carboquim ICB CSIC, Zaragoza 50018, Spain

来源：

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2014年 / 56卷 / 02期

关键词：

Ammonia decomposition; H-2; generation; Structured reactor; Supported metal catalyst; COX-FREE HYDROGEN; DENSITY-FUNCTIONAL THEORY; CELL POWER-SUPPLIES; NH3; DECOMPOSITION; STRUCTURE SENSITIVITY; RU CATALYSTS; BIMETALLIC CATALYSTS; RUTHENIUM CATALYSTS; SURFACE SEGREGATION; CARBON NANOTUBES;

D O I：

10.1080/01614940.2014.903637

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This perspective article focuses on the recent advances in the rational design of catalyst for NH3 decomposition at different length scales, from catalyst nanoparticles to reactor design. For an overall optimum performance, all scales should be optimized in a concerted manner. The study of the mechanism of reaction has given guidelines for the catalyst design. As far as reactor design is concerned, a structured reactor is beneficial for this reaction because it minimizes the inhibiting effect of produced H-2, besides other inherent advantages. This holistic optimization of catalysts is expected to pave the way for application of NH3 as H-2 storage media.

引用

页码：220 / 237

页数：18

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