Dual magnetic behavior of dysprosium(III) molecular magnet and Co(II) spin-crossover in an isolated [3d]-[4f] compound

被引:2
|
作者
Xie, Xianqing [1 ]
Yang, Lixiao [2 ]
Luo, Feng [2 ]
机构
[1] Jiangxi Normal Univ, Natl Engn Res Ctr Carbohydrate Synth, Nanchang 330027, Jiangxi, Peoples R China
[2] East China Univ Technol, Coll Biol Chem & Mat Sci, Fuzhou 344000, Jiangxi, Peoples R China
关键词
Molecular design; Dy(III) molecular magnet; Spin crossover; Dual magnetic behavior; EFFICIENT SEPARATION; GAS-ADSORPTION; TRANSITION;
D O I
10.1016/j.inoche.2019.04.030
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A highly rare case showing the coexistence of Dy(III) molecular magnet and Co(H) spin-crossover (SCO) is designed and prepared by the metal-isolated [3d]-[4f] charge-balanced method, capable of as an effective pathway for generally applying to generate dual magnetic behavior and even multiple magnetic materials. A diamagnetic ion replaced method is further developed to characterize this special magnetic phenomenon.
引用
收藏
页码:93 / 96
页数:4
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