Inner valence region of CO+ studied by threshold photoelectron-photoion coincidence spectroscopy

被引:8
|
作者
Hikosaka, Y
Ahmad, M
Lablanquie, P
Penent, F
Hall, RI
Eland, JHD
机构
[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
[2] Inst Mat Struct Sci, Photon Factory, Tsukuba, Ibaraki 3050801, Japan
[3] Univ Paris 06, DIAM, F-75252 Paris, France
[4] Ctr Univ Paris Sud, LURE, F-91898 Orsay, France
基金
日本学术振兴会; 英国工程与自然科学研究理事会;
关键词
threshold photoelectrons; coincidences; inner valence;
D O I
10.1016/S0368-2048(02)00089-0
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
High-resolution threshold electron spectroscopy has been applied to CO in the photon energy region 26-40 eV, where many sharp and broad CO+ states are observed. Dissociation of CO+ states in the photon energy range 30-40 eV has been investigated by threshold photoelectron-ion coincidence spectroscopy. Fragmentation characteristics of several distinct CO+ states, which are interpreted as Rydberg states converging to CO2+ states, are found to be state-specific, and are not the same as those of the underlying broad bands corresponding to valence excited CO+ states. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:99 / 106
页数:8
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