Determination and evaluation of the second-order rate constants for the oxidation of maleic and fumaric acid derivatives with alkaline potassium permanganate

被引：0

作者：

Halim, S. Rahimah Abdul ^{[1
]}

French, Gilly M. ^{[1
]}

Hughes, Alexandra J. N. ^{[1
]}

Smith, C. A. Olivia Prankerd ^{[1
]}

Hughes, D. E. Peter ^{[1
]}

机构：

[1] Westminster Sch, London SW1P 3PB, England

来源：

JOURNAL OF CHEMICAL RESEARCH | 2009年 / 03期

关键词：

butenedioic acid; alkaline permanganate; oxidation; tartaric acid; MECHANISM;

D O I：

10.3184/030823409X424867

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The second-order rate constants for the oxidation of maleic (Z-butenedioc) and fumaric (E-butenedioc) acid derivatives by potassium permanganate at pH 13 were determined. These constants varied by a factor of 10(4). The results suggested that the rates of attack of the permanganate ion on the double bonds were largely governed by steric factors with electrostatic and electronic effects playing only a minor role.

引用

页码：188 / 190

页数：3

共 12 条

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