Sensitization of NaMO3 (M: Nb and Ta) Photocatalysts with Wide Band Gaps to Visible Light by Ir Doping

被引：61

作者：

Iwase, Akihide ^{[1
]}

Saito, Kenji ^{[1
]}

Kudo, Akihiko ^{[1
]}

机构：

[1] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2009年 / 82卷 / 04期

基金：

日本学术振兴会;

关键词：

SRTIO3; PHOTOCATALYSTS; O-2; EVOLUTION; H-2; IRRADIATION; WATER; TIO2; DECOMPOSITION; ANTIMONY; CHROMIUM; CATALYST;

D O I：

10.1246/bcsj.82.514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NiO/NaNbO3 (BG: 3.5 eV) showed photocatalytic activity for water splitting into H-2 and O-2 under UV irradiation. When NaMO3 (M: Nb and Ta) was codoped with iridium ions and alkaline earth metal ions or lanthanum ions, a new visible-light absorption band was observed in addition to the band gap absorption band of the host material. The codopants of alkaline earth metal and lanthanum ions contributed to maintaining the charge balance and forming of fine crystals of the NaMO3 powder. These NaNbO3 and NaTaO3 codoped with iridium ions and alkaline earth metal ions or lanthanum ions showed photocatalytic activities for H-2 or O-2 evolution from an aqueous solution containing a sacrificial reagent under visible light irradiation.

引用

页码：514 / 518

页数：5

共 20 条

[1] Sensitization of NaMO3 (M: Nb and Ta) photocatalysts with wide band gaps to visible light by Ir doping
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
Bull. Chem. Soc. Jpn., 4 (514-518):
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[5] Synthesis of new visible light active photocatalysts of Ba(In1/3Pb1/3M1/3)O3 (M′ = Nb, Ta):: A band gap engineering strategy based on electronegativity of a metal component
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[6] Modification of NiTiO3 visible light-driven photocatalysts by Nb doping and NbOx heterojunction: Oxygen vacancy in the Nb-doped NiTiO3 structure
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[7] Modification of NiTiO3 visible light-driven photocatalysts by Nb doping and NbOx heterojunction: Oxygen vacancy in the Nb-doped NiTiO3 structure
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[8] K4Ce2M10O30 (M = Ta, Nb) as visible light-driven photocatalysts for hydrogen evolution from water decomposition
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[9] Synthesis of new visible light active photocatalysts of Ba(In1/3Pb1/3M′1/3)O3 (M′ = Nb, Ta):: A band gap engineering strategy based on electronegativity of a metal component (vol 109, pg 15001, 2005)
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[10] Dopant dependent band gap tailoring of hydrothermally prepared cubic SrTixM1-xO3 (M=Ru,Rh,Ir,Pt,Pd) nanoparticles as visible light photocatalysts
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