Asymmetric epoxidation of chiral allylic alcohols

被引：12
|
作者：
Warmerdam, EGJC
vandenNieuwendijk, AMCH
Brussee, J
Kruse, CG
vanderGen, A
机构：
[1] LEIDEN UNIV,LEIDEN INST CHEM,GORLAEUS LABS,NL-2300 RA LEIDEN,NETHERLANDS
[2] SOLVAY DUPHAR BV,NL-1380 DA WEESP,NETHERLANDS
来源：
TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 09期
关键词：
D O I：
10.1016/0957-4166(96)00327-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two series of chiral allylic alcohols, derived from alpha,beta-unsaturated cyanohydrins, were subjected to asymmetric epoxidation under a variety of conditions. Both achiral (organic peracid, metal-catalyzed peroxide) and chiral (Sharpless titanium-tartrate system) oxidants were applied. Several three and all theoretically possible erythro epoxides were isolated in enantiomerically and diastereomerically pure form. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：2539 / 2550
页数：12
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