Synthesis, characterization, and catalytic behavior of ruthenium(II) Schiff base complexes

被引：48
|
作者：
Serron, SA
Haar, CM
Nolan, SP
Brammer, L
机构：
[1] UNIV NEW ORLEANS,DEPT CHEM,NEW ORLEANS,LA 70148
[2] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 23期
关键词：
D O I：
10.1021/om970600f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complexes (X-6-acen)Ru(PPh3)(2) (X = H (1) and F (2)) have been prepared and characterized by standard spectroscopic and analytical methods. Additionally, the solid-state structure of 2 has been determined by single-crystal X-ray diffraction. Ligand exchange reactions involving the labile Ru-PPh3 bond are easily performed, and complex 1 serves as a catalyst precursor for the isomerization of 1-hexene.
引用
收藏
页码：5120 / 5123
页数：4
相关论文
共 50 条
  • [1] Synthesis, characterization and catalytic studies of ruthenium(II) Schiff base complexes
    Kanchanadevi, S
    Balasubramanian, KP
    Chinnusamy, V
    Karvembu, R
    Natarajan, K
    TRANSITION METAL CHEMISTRY, 2005, 30 (03) : 330 - 333
  • [2] Synthesis, characterization and catalytic studies of ruthenium(II) Schiff base complexes
    Sivasamy Kanchanadevi
    Kugalur P. Balasubramanian
    Vaiyapuri Chinnusamy
    Ramasamy Karvembu
    Karuppannan Natarajan
    Transition Metal Chemistry, 2005, 30 : 330 - 333
  • [3] Synthesis and characterization of some ruthenium(II) Schiff base complexes
    Bhowon, MG
    Nedhool, D
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1999, 29 (04): : 607 - 620
  • [4] Chiral schiff base ruthenium(II) carbonyl complexes: Synthesis, characterization, catalytic and antibacterial studies
    Thangadurai, T. Daniel
    Ihm, Son-Ki
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2006, 36 (05) : 435 - 440
  • [5] Synthesis, characterization and biological activities of ruthenium(II) Schiff base complexes
    Periyasamy, M
    Balasubramanian, KP
    Chinnusamy, V
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2004, 43 (10): : 2132 - 2136
  • [6] Synthesis, characterization, electrochemical, catalytic and antimicrobial activity studies of hydrazone Schiff base ruthenium(II) complexes
    Thilagavathi, N.
    Manimaran, A.
    Priya, N. Padma
    Sathya, N.
    Jayabalakrishnan, C.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (04) : 301 - 307
  • [7] Schiff base complexes of ruthenium(II) and their use as catalytic oxidants
    Bhowon, MG
    Wah, HLK
    Narain, R
    POLYHEDRON, 1999, 18 (3-4) : 341 - 345
  • [8] SYNTHESIS AND CHARACTERIZATION OF RUTHENIUM(II) SCHIFF-BASE CARBONYL-COMPLEXES
    KHAN, MMT
    SHAIKH, ZA
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1992, 31 (03): : 191 - 194
  • [9] Synthesis, spectral, and catalytic studies of ruthenium(II) unsymmetrical Schiff-base complexes
    Gowri, S.
    Priya, J.
    Muthukumar, M.
    Viswanathamurthi, P.
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (08) : 1320 - 1326
  • [10] Ruthenium(II) hydrazone Schiff base complexes: Synthesis, spectral study and catalytic applications
    Manikandan, R.
    Viswanathamurthi, P.
    Muthukumar, M.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 83 (01) : 297 - 303
12345