Electrochemical Oxidative Arylsulfonylation and 1,2-Alkyl Shift Sequences of Alkenyl Cyclobutanols for the Synthesis of β-Sulfonated Cyclopentanones

被引：17
|
作者：
Kim, Yebin [1 ,2 ]
Kim, Dae Young [1 ,2 ]
机构：
[1] Soonchunhyang Univ, Dept Chem, Asan 31538, Chungnam, South Korea
[2] Soonchunhyang Univ, Dept ICT Environm Hlth Syst, Asan 31538, Chungnam, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2021年 / 42卷 / 03期
基金：
新加坡国家研究基金会;
关键词：
Electrochemical oxidation; Sulfonylation; Vinyl cyclobutanols; beta-Sulfonated cyclopentanones; Semipinacol rearrangement; VISIBLE-LIGHT PHOTOREDOX; MIGRATION SEQUENCES; RING EXPANSION; SEMIPINACOL REARRANGEMENTS; ELECTROCATALYTIC APPROACH; DIFUNCTIONALIZATION; QUINOXALIN-2(1H)-ONES; SULFONYLATION; CYCLIZATION; ARYLATION;
D O I：
10.1002/bkcs.12218
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel process for the synthesis of beta-sulfonated cyclopentanones via electrochemical oxidative radical arylsulfonylation and 1,2-alkyl shift sequences of vinyl cyclobutanols was successfully developed. This approach represents a practical method for the preparation of beta-sulfonated cyclopentanones under environmentally benign reaction conditions.
引用
收藏
页码：510 / 513
页数：4
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