Synthesis of liverwort sesquiterpene (-)-isocuparene(herbertene) via a Diels-Alder reaction using phenylethylamine as chiral auxiliary

被引：24
|
作者：
Tori, M
Miyake, T
Hamaguchi, T
Sono, M
机构：
[1] Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima 770, Yamashiro cho
来源：
TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 16期
关键词：
D O I：
10.1016/S0957-4166(97)00313-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The imine of 2-methylcyclopentanone with (S)(-)-phenylethylamine was subjected to reaction with methyl propiolate and the product was transformed into (-)-isocuparene by use of a Diels-Alder reaction to construct the aromatic ring. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：2731 / 2738
页数：8
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