Three-Dimensional Branched and Faceted Gold-Ruthenium Nanoparticles: Using Nanostructure to Improve Stability in Oxygen Evolution Electrocatalysis

被引:91
|
作者
Gloag, Lucy [1 ]
Benedetti, Tania M. [1 ]
Cheong, Soshan [2 ]
Li, Yibing [1 ]
Chan, Xuan-Hao [3 ,4 ]
Lacroix, Lise-Marie [5 ]
Chang, Shery L. Y. [6 ]
Arenal, Raul [7 ,8 ]
Florea, Ileana [9 ]
Barron, Hector [10 ]
Barnard, Amanda S. [10 ]
Henning, Anna M. [3 ,4 ]
Zhao, Chuan [1 ]
Schuhmann, Wolfgang [11 ]
Gooding, J. Justin [1 ,12 ,13 ]
Tilley, Richard D. [1 ,2 ,13 ]
机构
[1] Univ New South Wales, Sch Chem, Sydney, NSW 2052, Australia
[2] Univ New South Wales, Electron Microscope Unit, Mark Wainwright Analyt Ctr, Sydney, NSW 2052, Australia
[3] Victoria Univ Wellington, Sch Chem & Phys Sci, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington 6012, New Zealand
[4] Victoria Univ Wellington, Boutiq Sci Ltd, Wellington 6012, New Zealand
[5] Univ Toulouse, LPCNO, CNRS, INSA,UPS, 135 Ave Rangueil, F-31077 Toulouse, France
[6] Arizona State Univ, LeRoy Eyring Ctr Solid Sci, Tempe, AZ USA
[7] Univ Zaragoza, Lab Microscopias Avanzadas, Inst Nanociencia Aragon, Calle Mariano de Luna, Zaragoza 50018, Spain
[8] Univ Zaragoza, ARAID Fundat, Calle Mariano de Luna, Zaragoza 50018, Spain
[9] Univ Paris Saclay, CNRS, Ecole Polytech, LPICM, F-91128 Palaiseau, France
[10] CSIRO Mol & Mat Modelling, Data61 Door 24 Village St, Docklands, Vic 2008, Australia
[11] Ruhr Univ Bochum, Analyt Chem Ctr Electrochem Sci, D-44780 Bochum, Germany
[12] Univ New South Wales, Australian Ctr NanoMed, Sydney, NSW 2052, Australia
[13] Univ New South Wales, ARC Ctr Excellence Convergent Bionano Sci & Techn, Sydney, NSW 2052, Australia
基金
欧盟地平线“2020”;
关键词
bimetallic nanoparticles; electrocatalysis; nanocrystals; oxygen evolution; ruthenium; PT BIMETALLIC NANODENDRITES; HCP RUTHENIUM; GROWTH; NANOCRYSTALS; SURFACE; RU; IR;
D O I
10.1002/anie.201806300
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Achieving stability with highly active Ru nanoparticles for electrocatalysis is a major challenge for the oxygen evolution reaction. As improved stability of Ru catalysts has been shown for bulk surfaces with low-index facets, there is an opportunity to incorporate these stable facets into Ru nanoparticles. Now, a new solution synthesis is presented in which hexagonal close-packed structured Ru is grown on Au to form nanoparticles with 3D branches. Exposing low-index facets on these 3D branches creates stable reaction kinetics to achieve high activity and the highest stability observed for Ru nanoparticle oxygen evolution reaction catalysts. These design principles provide a synthetic strategy to achieve stable and active electrocatalysts.
引用
收藏
页码:10241 / 10245
页数:5
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