Enhanced electrochemical CO2-to-C2+ conversion from synergistic interaction between terrace and step sites on monocrystalline high-index Cu facets

被引：12

作者：

Zhu, Chenyuan ^{[1
,2
]}

Zhang, Zhibin ^{[3
]}

Zhong, Lixiang ^{[4
]}

Zhao, Siwen ^{[1
,2
]}

Shi, Guoshuai ^{[1
,2
]}

Wu, Bowen ^{[1
,2
]}

Gu, Huoliang ^{[1
,2
]}

Wu, Jing ^{[1
,2
]}

Gao, Xinyang ^{[1
,2
]}

Liu, Kaihui ^{[3
]}

Zhang, Liming ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200438, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200438, Peoples R China

[3] Peking Univ, Sch Phys, Frontiers Sci Ctr Nanooptoelect, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China

[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

来源：

JOURNAL OF ENERGY CHEMISTRY | 2022年 / 70卷

基金：

中国国家自然科学基金;

关键词：

CO2; reduction; Synergistic interaction; Copper; Terrace and step; Electrochemistry; CARBON-DIOXIDE; ELECTROCATALYTIC CONVERSION; CO2; REDUCTION; CATALYST; ELECTROREDUCTION; SELECTIVITY; INSIGHTS; SURFACES;

D O I：

10.1016/j.jechem.2022.02.027

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

引用

页码：382 / 387

页数：6

共 35 条

[1] Enhanced electrochemical CO2-to-C2+ conversion from synergistic interaction between terrace and step sites on monocrystalline highindex Cu facets
Chenyuan Zhu
Zhibin Zhang
Lixiang Zhong
Siwen Zhao
Guoshuai Shi
Bowen Wu
Huoliang Gu
Jing Wu
Xinyang Gao
Kaihui Liu
Liming Zhang
Journal of Energy Chemistry, 2022, 70 (07) : 382 - 387
[2] Dual atomic Cu sites enable CO2-to-C2+ conversion in strong acid
Zhou, Liyuan
Cao, Liucheng
Xia, Bao Yu
CHEM CATALYSIS, 2025, 5 (02):
[3] Electroreduction of CO2 on Au(310)@Cu High-index Facets
Liang, Liang
Feng, Quanchen
Wang, Xingli
Huebner, Jessica
Gernert, Ulrich
Heggen, Marc
Wu, Longfei
Hellmann, Tim
Hofmann, Jan P.
Strasser, Peter
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (12)
[4] Electrochemical Synthesis of Cu2O Concave Octahedrons with High-Index Facets and Enhanced Photoelectrochemical Activity
Liu, Chang
Chang, Ya-Huei
Chen, Jianan
Feng, Shien-Ping
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (44) : 39027 - 39033
[5] Pd-induced polarized Cu0-Cu+ sites for electrocatalytic CO2-to-C2+ conversion in acidic medium
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Song, Lu
Peng, Chen
Lv, Ximeng
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JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2024, 671 : 184 - 191
[6] Promoting C2+ Production from Electrochemical CO2 Reduction on Shape-Controlled Cuprous Oxide Nanocrystals with High-Index Facets
Fu, Wenli
Liu, Zhen
Wang, Tanyuan
Liang, Jiashun
Duan, Shuo
Xie, Linfeng
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ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (40) : 15223 - 15229
[7] Cu overlayers on tetrahexahedral Pd nanocrystals with high-index facets for CO2 electroreduction to alcohols
Zhang, Feng-Yang
Sheng, Tian
Tian, Na
Liu, Li
Xiao, Chi
Lu, Bang-An
Xu, Bin-Bin
Zhou, Zhi-You
Sun, Shi-Gang
CHEMICAL COMMUNICATIONS, 2017, 53 (57) : 8085 - 8088
[8] From low to high-index facets of noble metal nanocrystals: a way forward to enhance the performance of electrochemical CO2reduction
Woldu, Abebe Reda
NANOSCALE, 2020, 12 (16) : 8626 - 8635
[9] Differentiating the Impacts of Cu2O Initial Low- and High-Index Facets on Their Reconstruction and Catalytic Performance in Electrochemical CO2 Reduction Reaction
Han, Chen
Kundi, Varun
Ma, Zhipeng
Toe, Cui Ying
Kumar, Priyank
Tsounis, Constantine
Jiang, Junjie
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Amal, Rose
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ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (12)
[10] Impact of heterogeneous construction on the low- and high-index facets of Cu2O on the catalytic performance and reconstruction in the electrochemical CO2 reduction reaction
Guo, Jiaxing
Mu, Haiqiang
Lv, Zhenli
Ma, Guorui
Zheng, Zhiyu
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Li, Feng
Li, Jing
JOURNAL OF MATERIALS CHEMISTRY A, 2025, 13 (14) : 9899 - 9909

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