Reactions of platinum(II)-nitrile complexes with amines.: Synthesis, characterization and X-ray structure of the platinum (II)-amidine complex trans-[PtCl2{Z-N(H)=C(NHMe)Me}2]

被引：42
|
作者：
Bertani, R
Catanese, D
Michelin, RA
Mozzon, M
Bandoli, G
Dolmella, A
机构：
[1] Univ Padua, CNR, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy
[2] Univ Padua, CNR, Ctr Studio Chim & Tecnol Composti Met Organ Eleme, I-35131 Padua, Italy
[3] Univ Padua, Dipartimento Sci Farmaceut, I-35131 Padua, Italy
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 01期
关键词：
platinum complexes; nitrile complexes; amidine complexes; crystal structures;
D O I：
10.1016/S1387-7003(99)00174-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of trans-[PtCl2(NCMe)(2)] with a 5-fold excess of MeNH2 in CH2Cl2 at -10 degrees C affords in high yield the bis-amidine complex trans-[PtCl2{Z-N(H) = C(NHMe)Me}(2)] (1),where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the C = N triple band. Compound I has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：16 / 18
页数：3
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