A Mannich-type reaction in water employing a dendritic copper(II) triflate catalyst: A positive dendritic effect on chemical yield

被引：17
|
作者：
Muraki, Takahito [1 ]
Fujita, Ken-ichi [1 ]
Terakado, Dai [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, AIST, Tsukuba, Ibaraki 3058565, Japan
来源：
SYNLETT | 2006年 / 16期
关键词：
dendrimers; Lewis acids; multicomponent reaction; Mannich-type reaction; dendritic effect;
D O I：
10.1055/s-2006-951479
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A three-component Mannich-type reaction catalyzed by the Lewis acid-core metallodendrimers prepared from the dendritic 2,2 '-bipyridine ligands and Cu(OTf)(2) proceeded smoothly in water. A positive dendritic effect on the chemical yields of the Mannich products was observed.
引用
收藏
页码：2646 / 2648
页数：3
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