Condensation of all-cis-tetraphenylcyclotetrasiloxanetetraol in ammonia: new method for preparation of ladder-like polyphenylsilsesquioxanes

被引：17

作者：

Anisimov, Anton A. ^{[1
]}

Polshchikova, Natalia V. ^{[1
]}

Vysochinskaya, Yuliya S. ^{[1
,2
]}

Zader, Pavel A. ^{[3
]}

Nikiforova, Galina G. ^{[1
]}

Peregudov, Alexander S. ^{[1
]}

Buzin, Mikhail I. ^{[1
]}

Shchegolikhina, Olga I. ^{[1
]}

Muzafarov, Aziz M. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[2] Russian Acad Sci, NS Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia

[3] DI Mendeleev Univ Chem Technol Russia, Moscow 125047, Russia

来源：

MENDELEEV COMMUNICATIONS | 2019年 / 29卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

MOLECULAR-STRUCTURE; POLYCONDENSATION; POLYSILSESQUIOXANES;

D O I：

10.1016/j.mencom.2019.07.022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-step method for the preparation of polyphenylsilsesquioxane by condensation of all-cis-1,3,5,7-tetraphenyl-1,3,5,7-tetrahydroxycyclotetrasiloxane in liquid ammonia has been developed. This method makes it possible to produce high molecular weight polymers with regular structure in the absence of organic solvent. The structure of the polymer product was confirmed by H-1 and Si-29 NMR spectroscopy, GPC, IR spectroscopy, powder X-ray diffraction and viscosimetry.

引用

页码：421 / 423

页数：3

共 3 条

[1] Preparation and Characterization of Organic-norganic Hybrid Macrocyclic Compounds: Cyclic Ladder-like Polyphenylsilsesquioxanes
Zhang, Wenchao
Wang, Xiaoxia
Wu, Yiwei
Qi, Zhi
Yang, Rongjie
INORGANIC CHEMISTRY, 2018, 57 (07) : 3883 - 3892
[2] A Versatile Equilibrium Method for the Synthesis of High-Strength, Ladder-like Polyphenylsilsesquioxanes with Finely Tunable Molecular Parameters
Ershova, Tatyana O.
Anisimov, Anton A.
Temnikov, Maxim N.
Novikov, Maxim A.
Buzin, Mikhail I.
Nikiforova, Galina G.
Dyuzhikova, Yulia S.
Ushakov, Ivan E.
Shchegolikhina, Olga I.
Muzafarov, Aziz M.
POLYMERS, 2021, 13 (24)
[3] A new highly efficient method for the preparation of phenyl-containing siloxanes by condensation of phenylsilanols in liquid ammonia
Ershova, Tatyana
Anisimov, Anton
Krylov, Fedor
Polshchikova, Natalia
Temnikov, Maxim
Shchegolikhina, Olga
Muzafarov, Aziz
CHEMICAL ENGINEERING SCIENCE, 2022, 247

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