Pigments of fungi.: LV -: The absolute configuration of dermocanarin 4 and the structure and stereochemistry of the dermocanarins 5, 6, 8 and 9 from Australian toadstools belonging to the genus Cortinarius

被引：12

作者：

Elsworth, C ^{[1
]}

Gill, M ^{[1
]}

Milanovic, NM ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 09期

关键词：

D O I：

10.1071/CH99076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereochemistry in the dihydroanthracenone ring of dermocanarin 4 (1) is defined as (S) by incorporation of the gentiobioside (2) of (S)-[6-OMe-C-13]torosachrysone into the dihydroanthracenone ring of dermocanarin 4 by fruiting bodies of Cortinarius sinapicolor. In addition, the new dermocanarins 5 (3), 6 (4), 8 (5) and 9 (6) are isolated from two other indigenous toadstools belonging to Cortinarius and their structure and stereochemistry are deduced from the respective spectroscopic data and by comparison with dermocanarin 4 (1).

引用

页码：867 / 873

页数：7

共 6 条

[1] Pigments of fungi.: Part 51.: Structure and stereochemistry of coupled pre-anthraquinones of the pseudophlegmacin type from Australian toadstools belonging to the genus Dermocybe
Buchanan, MS
Gill, M
Millar, PA
Phonh-Axa, S
Raudies, E
Yu, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (07): : 795 - 801
[2] Pigments of fungi. XLVIII - Clavorubin from two Australasian toadstools of the genus Cortinarius and the X-ray crystal structure of the methyl ester of 6-O-methylclavorubin
Buchanan, MS
Gill, M
Milanovic, NM
Phonh-Axa, S
Steel, PJ
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (05) : 347 - 352
[3] Pigments of fungi.: Part 49.: Structure and biosynthesis of dermocanarin 4, a naphthoquinone-dihydroanthracenone dimer from the fungus Cortinarius sinapicolor Cleland
Gill, M
Gimenez, A
Jhingran, AG
Milanovic, NM
Palfreyman, AR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (20): : 3431 - 3436
[4] Biologically active metabolites from fungi .9. New palmarumycins CP4a, and CP5 from Coniothyrium palmarum: Structure elucidation, crystal structure analysis and determination of the absolute configuration by CD calculations
Krohn, K
Beckmann, K
Florke, U
Aust, HJ
Draeger, S
Schulz, B
Busemann, S
Bringmann, G
[J]. TETRAHEDRON, 1997, 53 (09) : 3101 - 3110
[5] STRUCTURE AND ABSOLUTE-CONFIGURATION OF A HIGH-AFFINITY 5-HT3 RECEPTOR ANTAGONIST, (5AS,9AS)-N-[(3S)-1-AZABICYCLO[2.2.2]OCTAN-3-YL]-2-CHLORO-5A,6,7,8,9,9A-HEXAHYDRO-4-DIBENZOFURANCARBOXAMIDE HYDROCHLORIDE
AMMON, HL
YOUSSEFYEH, RD
AIREY, JE
STUDT, WL
CAMPBELL, HF
POWERS, MR
GOLEC, FA
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1551 - 1554
[6] Absolute structure of (3aS,5S,7aS,7bS,9aR,10-S,5S,7aS,7bS,9aR,10R,12aR,12bS)-7b-hydroxy4,4,7a,9a,12a-pentamethyl-10-[(2′R)-6-methylheptan-2-yl]-2,8,9-trioxooctadecahydrobenzo[d]indeno[4,5-b] azepin-5-yl acetate from 62-year-old crystals
Suescun, Leopoldo
Heinzen, Horacio
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 1348 - +

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