Effects of electronic correlations for adiabatic electrochemical reactions of electron transfer in electrode models with nearly empty and nearly filled conduction bands: Diagram of kinetic modes

被引：1

作者：

Medvedev, IG ^{[1
]}

机构：

[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 119071, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2004年 / 40卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

electron transfer; adiabatic electron transfer; coulombic interaction; correlation effects; Anderson model;

D O I：

10.1023/B:RUEL.0000027617.32706.a4

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A diagram of kinetic modes (DKM), whose parts correspond to different electron transfer types, for any electrode's Fermi energy epsilon(F) and any finite value of its conduction band's width B is studied. Important differences between DKM for any epsilon(F) and B and DKM in a model of a surface molecule for an electrode-reactant system are pointed out. DKM for electrode models with nearly empty and nearly filled conduction bands proposed earlier are discussed. Expressions for outermost curves of DKM are derived for some special cases within these models.

引用

页码：479 / 489

页数：11

共 17 条

[1] Effects of Electronic Correlations for Adiabatic Electrochemical Reactions of Electron Transfer in Electrode Models with Nearly Empty and Nearly Filled Conduction Bands: Diagram of Kinetic Modes
I. G. Medvedev
[J]. Russian Journal of Electrochemistry, 2004, 40 : 479 - 489
[2] Effects of Electronic Correlations for Adiabatic Electrochemical Reactions of Electron Transfer in Electrode Models with Nearly Empty and Nearly Filled Conduction Bands: General Relationships
I. G. Medvedev
[J]. Russian Journal of Electrochemistry, 2004, 40 : 440 - 448
[3] Effects of electronic correlations for adiabatic electrochemical reactions of electron transfer in electrode models with nearly empty and nearly filled conduction bands: General relationships
Medvedev, IG
[J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2004, 40 (04) : 440 - 448
[4] Effects of Electronic Correlations for Adiabatic Electrochemical Reactions of Electron Transfer in Electrode Models with Nearly Empty and Nearly Filled Conduction Bands: Adiabatic Free Energy Surfaces
I. G. Medvedev
[J]. Russian Journal of Electrochemistry, 2004, 40 : 604 - 611
[5] Effects of electronic correlations for adiabatic electrochemical reactions of electron transfer in electrode models with nearly empty and nearly filled conduction bands: Adiabatic free energy surfaces
Medvedev, IG
[J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2004, 40 (06) : 604 - 611
[6] Electron Correlation Effects for Adiabatic Electrochemical Reactions of Electron Transfer in a Model for an Electrode with an Infinitely Wide Conduction Band: Diagrams of Kinetic Modes
A. M. Kuznetsov
I. G. Medvedev
V. V. Sokolov
[J]. Russian Journal of Electrochemistry, 2003, 39 : 839 - 851
[7] Electron correlation effects for adiabatic electrochemical reactions of electron transfer in a model for an electrode with an infinitely wide conduction band: Diagrams of kinetic modes
Kuznetsov, AM
Medvedev, IG
Sokolov, VV
[J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2003, 39 (08) : 839 - 851
[8] Effects of Electron Correlations in a Simple Model for Adiabatic Electrochemical Reactions: The Diagram of Kinetic Regimes
A. M. Kuznetsov
I. G. Medvedev
[J]. Russian Journal of Electrochemistry, 2001, 37 : 341 - 352
[9] Effects of electron correlations in a simple model for adiabatic electrochemical reactions: The diagram of kinetic regimes
Kuznetsov, AM
Medvedev, IG
[J]. RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2001, 37 (04) : 341 - 352
[10] Electron Correlations for Adiabatic Electrochemical Electron Transfer Reactions in a Model for an Electrode with an Infinitely Wide Conduction Band
I. G. Medvedev
[J]. Russian Journal of Electrochemistry, 2003, 39 : 44 - 53

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