Examples of Molecular Self-Assembly at Surfaces

被引：26
|
作者：
Whitelam, Stephen [1 ]
机构：
[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 38期
关键词：
self-assembly; statistical mechanics; surfaces; NETWORKS; LAYERS;
D O I：
10.1002/adma.201405573
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The self-assembly of molecules at surfaces can be caused by a range of physical mechanisms. Assembly can be driven by intermolecular forces, or molecule-surface forces, or both; it can result in structures that are in equilibrium or that are kinetically trapped. Here we review examples of self-assembly at surfaces focusing on a physical understanding of what causes patterns seen in experiment. Some apparently disparate systems can be described in similar physical terms, indicating that simple factors - such as the geometry and energy scale of intermolecular binding - are key to understanding the self-assembly of those systems.
引用
收藏
页码：5720 / 5725
页数：6
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