Versatile chain transfer agents for reversible addition fragmentation chain transfer (RAFT) polymerization to synthesize functional polymeric architectures

被引：178
|
作者：
Perrier, S [1 ]
Takolpuckdee, P [1 ]
Westwood, J [1 ]
Lewis, DM [1 ]
机构：
[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
MACROMOLECULES | 2004年 / 37卷 / 08期
关键词：
D O I：
10.1021/ma035468b
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the syntheses and uses of versatile chain transfer agents (CTAs) that produce well-controlled macromolecular architectures with specific chain-end functionalities, via reversible addition fragmentation chain transfer (RAFT) polymerization). Examples of architectures are given, including amphiphilic copolymers and block copolymers incorporating a biodegradable block. These CTAs are also used for the grafting of poly(styrene), poly(methyl methacrylate) and poly(methyl acrylate) from cotton.
引用
收藏
页码：2709 / 2717
页数：9
相关论文
共 50 条
  • [1] Polymer architectures via reversible addition fragmentation chain transfer (RAFT) polymerization
    Takolpuckdee, P
    Westwood, J
    Lewis, DM
    Perrier, S
    [J]. MACROMOLECULAR SYMPOSIA, 2004, 216 : 23 - 35
  • [2] Synthesis of novel architectures by radical polymerization with reversible addition fragmentation chain transfer (RAFT polymerization)
    Moad, G
    Mayadunne, RTA
    Rizzardo, E
    Skidmore, M
    Thang, SH
    [J]. MACROMOLECULAR SYMPOSIA, 2003, 192 : 1 - 12
  • [3] Living radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization) using dithiocarbamates as chain transfer agents
    Mayadunne, RTA
    Rizzardo, E
    Chiefari, J
    Chong, YK
    Moad, G
    Thang, SH
    [J]. MACROMOLECULES, 1999, 32 (21) : 6977 - 6980
  • [4] Triblock copolymers for functional polymeric materials: Synthesis by reversible addition-fragmentation chain transfer (RAFT) polymerization
    Legge, Thomas Martyn
    Perrier, Sebastien
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U4234 - U4235
  • [5] Photoregulated reversible addition-fragmentation chain transfer (RAFT) polymerization
    Li, Shenzhen
    Han, Guang
    Zhang, Wangqing
    [J]. POLYMER CHEMISTRY, 2020, 11 (11) : 1830 - 1844
  • [6] Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization with a Polymeric RAFT Agent Containing Multiple Trithiocarbonate Groups
    Liu, Yuqing
    Cavicchi, Kevin A.
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (19) : 1647 - 1653
  • [7] Reversible Addition-Fragmentation Chain Transfer: RAFT
    不详
    [J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2023, 81 (04) : 381 - 381
  • [8] Reversible addition-fragmentation chain transfer (RAFT) polymerization of styrene using novel heterocycle-containing chain transfer agents
    Babu, Rajendran Prakash
    Dhamodharan, Raghavachari
    [J]. POLYMER INTERNATIONAL, 2008, 57 (02) : 365 - 371
  • [9] 'Green' reversible addition-fragmentation chain-transfer (RAFT) polymerization
    Semsarilar, Mona
    Perrier, Sebastien
    [J]. NATURE CHEMISTRY, 2010, 2 (10) : 811 - 820
  • [10] Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)
    Dommanget, Cedric
    D'Agosto, Franck
    Monteil, Vincent
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (26) : 6683 - 6686
12345