{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ4O6,O1,O1′,O6′:2κ4O1,N,N′,O1′}(methanol-1κO)(perchlorato-1κO)nickel(II)sodium

被引：6
|
作者：
Xiao, Hui-Quan [1 ]
机构：
[1] Shaoxing Univ, Dept Chem, Shaoxing 312000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
COMPLEXES;
D O I：
10.1107/S1600536809007776
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecule of the title compound, [NaNi(C18H18N2O4)(ClO4)(CH3OH)], is almost planar, the maximum deviation from the molecular plane being 5.3 (1) angstrom. The Ni2+ ion is N2O2 coordinated by the Schiff base ligand, leading to a slightly distorted square-planar environment. The Na atom is chelated by the four O atoms of the Schiff base ligand and is coordinated by the O atoms of a methanol ligand and a perchlorate anion. The perchlorate ion is disordered over two sites with occupancies 0.723 (12): 0.277 (12).
引用
收藏
页码：M400 / U529
页数：10
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