Ammonium salts with polyether-tail: new ionic liquids for rhodium catalyzed two-phase hydroformylation of 1-tetradecene

被引：17
|
作者：
Kong, FZ [1 ]
Jiang, JY [1 ]
Jin, ZL [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
来源：
CATALYSIS LETTERS | 2004年 / 96卷 / 1-2期
关键词：
ionic liquid; polyether; hydroformylation; two-phase;
D O I：
10.1023/B:CATL.0000029530.59982.27
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By attaching the polyether chains to ammonium salts, a novel class of ionic liquid termed polyether melt is prepared. Such polyether melt contains no fluoride and hence is environmentally more benign. Applying this polyether melt as a polar phase, the hydroformylation of 1-tetradecene catalyzed by Rh complex catalyst in two-phase medium was investigated. The rhodium catalyst immobilized in this polyether melt is readily separated from the aldehyde product phase by decantation and has been reused for seven times without obvious loss of activity.
引用
收藏
页码：63 / 65
页数：3
相关论文
共 43 条
  • [1] Ammonium Salts with Polyether-Tail: New Ionic Liquids for Rhodium Catalyzed Two-Phase Hydroformylation of 1-Tetradecene
    Fanzhi Kong
    Jingyang Jiang
    Zilin Jin
    Catalysis Letters, 2004, 96 : 63 - 65
  • [2] The use of new ionic liquids in two-phase catalytic hydrogenation reaction by rhodium complexes
    Suarez, PAZ
    Dullius, JEL
    Einloft, S
    DeSouza, RF
    Dupont, J
    POLYHEDRON, 1996, 15 (07) : 1217 - 1219
  • [3] 1-dodecene hydroformylation catalyzed by water soluble rhodium phosphine complex in two-phase system
    Li, YZ
    Chen, H
    Chen, JR
    Cheng, PM
    Hu, JY
    Li, XJ
    CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (01) : 58 - 62
  • [4] Hydroformylation of long-chain olefins catalyzed by rhodium-phosphine complexes in new ionic liquids
    Lin, Q
    Fu, HY
    Xue, F
    Yuan, ML
    Chen, H
    Li, XJ
    ACTA PHYSICO-CHIMICA SINICA, 2006, 22 (04) : 465 - 469
  • [5] Hydroformylation of 1-hexene in ionic liquids catalyzed by highly active rhodium-phosphine complexes
    Zheng, HJ
    Li, M
    Chen, H
    Li, RX
    Li, XJ
    CHINESE JOURNAL OF CATALYSIS, 2005, 26 (01) : 4 - 6
  • [6] A novel class of versatile solvents for two-phase catalysis: Hydrogenation, isomerization, and hydroformylation of alkenes catalyzed by rhodium complexes in liquid 1,3-dialkylimidazolium salts
    Chauvin, Y
    Mussmann, L
    Olivier, H
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (23-24) : 2698 - 2700
  • [7] A novel class of versatile solvents for two-phase catalysis: Hydrogenation, isomerization, and hydroformylation of alkenes catalyzed by rhodium complexes in liquid 1,3-dialkylimidazolium salts
    Institut Français du Pétrole, Boîte Postale 311, F-92506 Rueil-Malmaison, France
    Angewandte Chemie (International Edition in English), 1996, 34 (23-24): : 2698 - 2700
  • [8] Thermoregulated phase transfer ligands and catalysis .1. Synthesis of novel polyether-substituted triphenylphosphines and application of their rhodium complexes in two-phase hydroformylation
    Jin, ZL
    Zheng, XL
    Fell, B
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) : 55 - 58
  • [9] Extraction of succinic acid by aqueous two-phase system using alcohols/salts and ionic liquids/salts
    Pratiwi, Aulia Indah
    Yokouchi, Takeyuki
    Matsumoto, Michiaki
    Kondo, Kazuo
    SEPARATION AND PURIFICATION TECHNOLOGY, 2015, 155 : 127 - 132
  • [10] Extraction of bioactive ginseng saponins using aqueous two-phase systems of ionic liquids and salts
    He, Ai
    Dong, Bing
    Feng, Xueting
    Yao, Shun
    SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 196 : 270 - 280
12345