Synthesis, structures, and UV-visible absorption spectra of tri(9-anthryl)bismuthine derivatives

被引：10
|
作者：
Yamaguchi, S [1 ]
Shirasaka, T
Tamao, K
机构：
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
[2] JST, PRESTO, Kyoto 6110011, Japan
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 12期
关键词：
D O I：
10.1021/om020124f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tri(9-anthtyl)bismuthines 3 and their difluorobismuth derivatives 4 have been synthesized and their UV-visible absorption spectra have been determined. The change from the tricoordinate 3 to the pentacoordinate 4 causes a subtle blue-shift in the lambda(0-0) of the anthryl moieties due to the decreased intramolecular through-space interaction between the anthryl moieties. Among the compounds, tri(9-anthryl)difluorobismuth, 4a, forms unique cocrystals with chloroform that have a porous honeycomb packing structure due to the pi-stacking of the anthryl moieties.
引用
收藏
页码：2555 / 2558
页数：4
相关论文
共 50 条
  • [41] STUDIES ON NITROXIDES .9. UV-VISIBLE, IR, MASS-SPECTRA OF SOME PIPERIDINE NITROXIDES
    LIU, YC
    WONG, YK
    LIU, ZL
    ACTA CHIMICA SINICA, 1985, 43 (06) : 569 - 571
  • [42] First observation of infrared and UV-visible absorption spectra of adenine radical in low-temperature argon matrices
    Iizumi, Shota
    Ninomiya, Shinya
    Sekine, Masahiko
    Nakata, Munetaka
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1025 : 43 - 47
  • [43] Theoretical valence photoelectron and UV-visible absorption spectra of four stable conductive molecules obtained by MO calculations
    Takaoka, K
    Maeda, S
    Miura, H
    Otsuka, T
    Endo, K
    Chong, DP
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (01) : 43 - 51
  • [44] UV-VISIBLE SPECTROPHOTOMETER PROVIDED WITH A PHOTON-COUNTING SYSTEM FOR THE STUDIES OF VERY WEAK ABSORPTION-SPECTRA
    YAMAMOTO, N
    SAWADA, T
    TSUBOMURA, H
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1979, 52 (04) : 987 - 989
  • [45] Listening to what ambient aerosols have to say: Measuring UV-visible absorption spectra using photoacoustic spectroscopy
    Fischer, D.
    Phillips, Sabrina
    Smith, Geoffrey
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [46] Theoretical and experimental investigation of NMR, IR and UV-visible spectra of hydroxyl-substituted-4-chloromethylcoumarin derivatives
    Loarueng, Chutipapha
    Boekfa, Bundet
    Jarussophon, Suwatchai
    Pongwan, Pawinee
    Kaewchangwat, Narongpol
    Suttisintong, Khomson
    Jarussophon, Nongpanga
    ARKIVOC, 2019, : 116 - 127
  • [47] Investigation of the Effects of Substituents and Various Solvents on UV-Visible Spectra of 5-(Quinolinylmethylene)barbituric Acid Derivatives
    Canlica, Mevlude
    Beker, H. Kerim
    Akinci, Alper
    Kaban, Seniz
    ASIAN JOURNAL OF CHEMISTRY, 2009, 21 (05) : 3969 - 3975
  • [48] Probing the Aggregated State of 4-(9-Anthryl)-N,N-dimethylaniline by UV-Vis Absorption and Fluorescence Spectroscopy, Microscopy, and Crystallography
    Kanaparthi, Ravi Kumar
    Sarkar, Moloy
    Samanta, Anunay
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (46): : 15189 - 15195
  • [49] SYNTHESIS AND UV-VISIBLE ABSORPTION ENVELOPES OF PUSH-PULL POLYENES - MODEL STRUCTURES FOR POTENTIAL APPLICATIONS IN SOLITON SWITCHING AND NONLINEAR OPTICAL PHENOMENA
    SPANGLER, CW
    MCCOY, RK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 13 - ORGN
  • [50] Study on the contribution of different molecular weight species to the absorption UV-Visible spectra of flame-formed carbon species
    Russo, Carmela
    Stanzione, Fernando
    Ciajolo, Anna
    Tregrossi, Antonio
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2013, 34 : 3661 - 3668
12345