Synthesis, structures, and UV-visible absorption spectra of tri(9-anthryl)bismuthine derivatives

被引：10
|
作者：
Yamaguchi, S [1 ]
Shirasaka, T
Tamao, K
机构：
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
[2] JST, PRESTO, Kyoto 6110011, Japan
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 12期
关键词：
D O I：
10.1021/om020124f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tri(9-anthtyl)bismuthines 3 and their difluorobismuth derivatives 4 have been synthesized and their UV-visible absorption spectra have been determined. The change from the tricoordinate 3 to the pentacoordinate 4 causes a subtle blue-shift in the lambda(0-0) of the anthryl moieties due to the decreased intramolecular through-space interaction between the anthryl moieties. Among the compounds, tri(9-anthryl)difluorobismuth, 4a, forms unique cocrystals with chloroform that have a porous honeycomb packing structure due to the pi-stacking of the anthryl moieties.
引用
收藏
页码：2555 / 2558
页数：4
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