Fe3+ doped Chrysotile nanotubes have been synthesized by hydrothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Infrared spectroscopy (IR) and electron spin resonance (ESR), The XRD analysis indicates that the cell-parameter (b(0)) of chrysotile nanotubes minishes gradually along with higher Fe3+ content in the synthesized samples. A partial Fe3+ replacement for Si4+ and Mg2+ has been revealed by IR and SER studies. The TEM analysis indicates that the inner diameters for the chrysotile nanotubes and the doped ones is 6 similar to 8 nm and 8 similar to 15 nm, respectively.