Catalyst-free selenylation of imidazoheterocycles

被引:37
|
作者
Jana, Sourav [1 ]
Chakraborty, Amrita [1 ]
Mondal, Susmita [1 ]
Hajra, Alakananda [1 ]
机构
[1] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India
来源
RSC ADVANCES | 2015年 / 5卷 / 95期
关键词
ONE-POT SYNTHESIS; UNSYMMETRICAL DIARYL CHALCOGENIDES; C-H FUNCTIONALIZATION; METAL-FREE; ROOM-TEMPERATURE; N-HETEROCYCLES; EFFICIENT; SELENIDES; DICHALCOGENIDES; SULFENYLATION;
D O I
10.1039/c5ra16729a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, efficient, and practical method for the phenylselenylation of imidazo[1,2-a]pyridines via electrophilic substitution employing readily available phenylselenium bromide has been developed in aqueous media at roomtemperature. A library of 3-phenylselenylimidazo[1,2-a]pyridines has been synthesized employing this methodology with high yields. The present protocol is also applicable for the phenylselenylation of imidazo[2,1-b]thiazole and benzo[d]imidazo[2,1-b]-thiazole.
引用
收藏
页码:77534 / 77537
页数:4
相关论文
共 50 条
  • [1] Catalyst-Free Regioselective Sulfenylation of Imidazoheterocycles with Sulfonyl Hydrazides in Water
    Chowdhury, Soumyadeep Roy
    Fadikar, Pulak
    Ul Hoque, Injamam
    Maity, Soumitra
    [J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (02) : 332 - 336
  • [2] Catalyst-free selenylation/semipinacol rearrangement cascades of alkenyl cyclobutanols: synthesis of β-selenylated cyclopentanones
    Kim, Dae Young
    [J]. SYNTHETIC COMMUNICATIONS, 2019, 49 (17) : 2203 - 2209
  • [3] Four-component synthesis of 3-aminomethylated imidazoheterocycles in EtOH under catalyst-free, oxidant-free and mild conditions
    Gui, Qing-Wen
    Wang, Bin-Bin
    Zhu, Sha
    Li, Fu-Long
    Zhu, Meng-Xue
    Yi, Min
    Yu, Jia-Ling
    Wu, Zhi-Lin
    He, Wei-Min
    [J]. GREEN CHEMISTRY, 2021, 23 (12) : 4430 - 4434
  • [4] A catalyst-free future?
    Anon
    [J]. Process Engineering (London), 2002, 83 (02):
  • [5] Catalyst-free direct cross-dehydrogenative coupling of imidazoheterocycles with glyoxal hydrates: an efficient approach to 1,2-diketones
    Guo, Tao
    Fu, Xiang-Heng
    Zhang, Miao
    Li, Yu-Liu
    Ma, Yong-Cheng
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (12) : 3150 - 3158
  • [6] Nanowires go catalyst-free
    Gould, Paula
    [J]. NANO TODAY, 2008, 3 (3-4) : 10 - 10
  • [7] Catalyst-free selenylation of acylacetylenes with secondary phosphine selenides and water: A short-cut to bis(2-acylvinyl) selenides
    Volkov, Pavel A.
    Gusarova, Nina K.
    Khrapova, Kseniya O.
    Telezhkin, Anton A.
    Ivanova, Nina I.
    Albanov, Alexander I.
    Trofimov, Boris A.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 79 - 85
  • [8] Catalyst-free defluorinative alkylation of trifluoromethyls
    Huang, Yan
    Wan, Yuan-Cui
    Shao, Yu
    Zhan, Le-Wu
    Li, Bin-Dong
    Hou, Jing
    [J]. GREEN CHEMISTRY, 2023, 25 (20) : 8280 - 8285
  • [9] Self-healing and catalyst-free
    不详
    [J]. MATERIALS WORLD, 2008, 16 (02) : 6 - 6
  • [10] Catalyst-free synthesis of mullite nanosticks
    Zhao, Fujun
    Han, Linhai
    Liang, Long
    [J]. HIGH-PERFORMANCE CERAMICS V, PTS 1 AND 2, 2008, 368-372 : 812 - +