catena-poly[tetraaquazinc(II)-μ-benzene-1,4-dioxyacetato-κ2O:O′]

被引：1
|
作者：
Liu, JW [1 ]
Gao, S [1 ]
Huo, LH [1 ]
Zhao, H [1 ]
Zhao, JG [1 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804022007
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Zn(1,4-BDOA)(H2O)(4)](n) or [Zn(C10H8O6)(H2O)(4)](n) (where 1,4-BDOA(2-) is the benzene1,4-dioxyacetate dianion), the Zn-II atom and the 1,4-BDOA(2-) ligand build up a one-dimensional polymer chain along c. The Zn-II atom, located on an inversion center, shows an octahedral coordination geometry, defined by two carboxyl O atoms of different benzene-1,4-dioxyacetate ligands and four water molecules. Adjacent Zn-II atoms are bridged by bis-monodentate carboxylate groups of the centrosymmetric 1,4-BDOA(2-) ligands, to furnish the one-dimensional chain along the c axis; the Zn...Zn separation within the polymer is 14.717 (3) Angstrom. A hydrogen-bonded supramolecular architecture is formed via O-H...O intermolecular hydrogen bonds.
引用
收藏
页码：M1408 / M1410
页数：3
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