A two-dimensional copper(II) coordination polymer comprising discrete left-and right-handed helical chains

被引：39
|
作者：
Wang, RH [1 ]
Han, L [1 ]
Sun, YQ [1 ]
Gong, YQ [1 ]
Yuan, DQ [1 ]
Hong, MC [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 694卷 / 1-3期
关键词：
coordination polymer; copper(II); helical chain; hydrogen bonds;
D O I：
10.1016/j.molstruc.2004.02.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel two-dimensional copper(H) coordination polymer comprising discrete left-handed and right-handed helical chains bridged by 1,3-di(4-pyridyl)propane (dpp), [{Cu-2(dpp)(2)(H2O)(2)(dpa)(2)}(H2O)(2)(CH3OH)(2)]n (1) (H(2)dpa = diphenic acid), has been prepared and characterized by single-crystal X-ray diffraction analysis. The hydrogen bonding interactions between the adjacent layers extend 1 into a three-dimensional supramolecular architecture. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：79 / 83
页数：5
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