Influence of surface and acid properties of vanadia supported on ceria promoted with rice husk silica on cyclohexanol decomposition

被引:9
|
作者
Radhika, T. [1 ]
Sugunan, S. [1 ]
机构
[1] Cochin Univ Sci & Technol, Dept Appl Chem, Cochin 682022, Kerala, India
关键词
supported vanadia; ceria; rice husk silica; cyclohexanol decomposition;
D O I
10.1016/j.catcom.2006.01.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cyclohexanol decomposition activity of supported vanadia catalysts is ascribed to the high surface area, total acidity and interaction between supported vanadia and the amorphous support. Among the supported catalysts, the effect of vanadia over various Wt% V2O5 (210) loading indicates that the catalyst comprising of 6 wt% V2O5 exhibits higher acidity and decomposition activity. Structural characterization of the catalysts has been done by techniques like energy dispersive X-ray analysis, X-ray diffraction and BET surface area. Acidity of the catalysts has been measured by temperature programmed desorption using ammonia as a probe molecule and the results have been correlated with the activity of catalysts. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:528 / 533
页数:6
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