Ionization of 2,5-dimethylfuran by electron impact and resulting ion-parent molecule reactions

被引：11
|
作者：
Jiao, C. Q. [1 ]
Adams, S. F. [2 ]
Garscadden, A. [2 ]
机构：
[1] UES, Dayton, OH 45440 USA
[2] USAF, Res Lab, Wright Patterson AFB, OH 45433 USA
来源：
JOURNAL OF APPLIED PHYSICS | 2009年 / 106卷 / 01期
关键词：
argon; dissociation; electron impact ionisation; Fourier transform spectra; ion-molecule reactions; mass spectra; molecule-electron collisions; organic compounds; positive ions; reaction kinetics; spectrochemical analysis; RESONANCE MASS-SPECTROMETRY; FRAGMENTATION; EXCITATION; PHASE;
D O I：
10.1063/1.3159009
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
2,5-dimethylfuran (C(6)H(8)O) is an important fuel additive and a possible renewable liquid fuel for the future. This paper presents a recent Fourier transfer mass spectrometry study on the formation of ions from C(6)H(8)O by electron impact ionization and by ion-molecule reactions. Cross sections of the partial electron impact ionization have been measured and the pathways of major fragmentation channels of the parent ion have been examined. The kinetics of the reactions of C(6)H(8)O with selected product ions from electron impact and Ar(+) have been studied.
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页数：4
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