Chemical Recycling of Carbon Fiber Reinforced Epoxy Resin Composites via Selective Cleavage of the Carbon-Nitrogen Bond

被引：150

作者：

Wang, Yuqi ^{[1
,2
]}

Cui, Xiaojing ^{[1
]}

Ge, Hui ^{[1
]}

Yang, Yongxing ^{[1
]}

Wang, Yingxiong ^{[1
]}

Zhang, Ce ^{[2
,3
]}

Li, Jingjing ^{[3
]}

Deng, Tiansheng ^{[1
]}

Qin, Zhangfeng ^{[1
]}

Hou, Xianglin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, Biorefinery Res & Engn Ctr, Taiyuan 030001, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2015年 / 3卷 / 12期

关键词：

Chemical recycling; Epoxy resin; Carbon fiber; Selective C-N bond cleavage; PRINTED-CIRCUIT BOARDS; NEAR-CRITICAL WATER; SUPERCRITICAL WATER; IONIC LIQUID; NITRIC-ACID; WASTE; POLYMERS; RECOVERY; DECOMPOSITION; TECHNOLOGIES;

D O I：

10.1021/acssuschemeng.5b00949

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient strategy is developed for chemical recycling of cured epoxy resin (CEP) from its carbon fiber reinforced polymer composites (CFREP) using AlCl3/CH3COOH as the degradation system. Acetic acid swells the dense structures of CEP, facilitating the penetration of the aluminum ion catalyst into the polymer matrix. The weakly coordinating aluminum ions in CH3COOH solution selectively cleave the C-N bond while leaving the C-C, C-O (aryl alkyl ether) bonds intact. This process recovers valuable oligomers and carbon fibers from CFREP.

引用

页码：3332 / 3337

页数：6

共 50 条

[1] REVIEW OF CHEMICAL RECYCLING AND REUSE OF CARBON FIBER REINFORCED EPOXY RESIN COMPOSITES
Tian, Zi-shang
Wang, Yu-qi
Hou, Xiang-lin
CARBON, 2023, 203 : 897 - 897
[2] Review of chemical recycling and reuse of carbon fiber reinforced epoxy resin composites
Tian, Zi-shang
Wang, Yu-qi
Hou, Xiang-lin
NEW CARBON MATERIALS, 2022, 37 (06) : 1021 - 1041
[3] Thermochemical recycling of epoxy resin composites reinforced with carbon fiber
Nicolai, Gabriel
Boas, Augusto P., V
Mendez, Manoel O. A.
Taranto, Osvaldir P.
JOURNAL OF COMPOSITE MATERIALS, 2023, 57 (20) : 3201 - 3212
[4] Controlling degradation and recycling of carbon fiber reinforced bismaleimide resin composites via selective cleavage of imide bonds
Zhao, Qi
Li, Xudong
Tian, Zishang
Ma, Hui
Hou, Xianglin
Wang, Yingxiong
Wang, Yuqi
COMPOSITES PART B-ENGINEERING, 2022, 231
[5] Progress in Chemical Recycling of Carbon Fiber Reinforced Epoxy Composites
Liu, Tuan
Shao, Lin
Zhao, Baoming
Chang, Yu-Chung
Zhang, Jinwen
MACROMOLECULAR RAPID COMMUNICATIONS, 2022, 43 (23)
[6] Chemical degradation and recovery of carbon fiber reinforced epoxy resin matrix composites containing ester bond
Zhang Y.
Zhang J.
Ma C.
Sun Z.
Wang Y.
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica, 2023, 40 (09): : 5026 - 5034
[7] Pretreatment of carbon fiber reinforced epoxy resin composites by laser selective ablation
Li, Chang-Qing (li_chq@sohu.com), 1600, Chinese Mechanical Engineering Society (29):
[8] Chemical Recycling of Carbon Fiber Reinforced Epoxy Composites Using Mild Conditions
Schamel, Elisabeth
Wehnert, Gerd
Schlachter, Herbert
Soethje, Dominik
CHEMIE INGENIEUR TECHNIK, 2021, 93 (10) : 1619 - 1628
[9] Chemical recycling of carbon fibers reinforced epoxy resin composites in oxygen in supercritical water
Bai, Yongping
Wang, Zhi
Feng, Liqun
MATERIALS & DESIGN, 2010, 31 (02) : 999 - 1002
[10] Chemical recycling of unsaturated polyester resin and its composites via selective cleavage of the ester bond
Wang, Yuqi
Cui, Xiaojing
Yang, Qiqi
Deng, Tiansheng
Wang, Yingxiong
Yang, Yongxing
Jia, Shiyu
Qin, Zhangfeng
Hou, Xianglin
GREEN CHEMISTRY, 2015, 17 (09) : 4527 - 4532

← 1 2 3 4 5 →