Characterization of a novel binuclear palladium(II) complex formed from the reaction of 2-chloro-3,3-diphenyl-1-(2,4,6-tri-tert-butylphenyl)-1,3-diphosphapropene with tetrakis(triphenylphosphine)palladium(0) including hydrolysis

被引：10

作者：

Liang, H ^{[1
]}

Ito, S ^{[1
]}

Yoshifuji, M ^{[1
]}

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Sendai, Miyagi 9808578, Japan

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 8-9期

关键词：

phosphaalkenes; steric hindrance; palladium; tridentate ligands;

D O I：

10.1002/zaac.200300423

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2-Chloro-3,3-diphenyl-1-(2,4,6-tri-tert-butylphenyl)-1,3-diphosphapropene was allowed to react with an equivalent amount of tetrakis(triphenylphosphine)palladium(0) and a novel binuclear palladium(II) complex which includes two P2O-tridentate ligands [Mes*P(O)CH2PPh2](2)[PdCl](2) (Mes* = 2,4,6-tBu(3)C(6)H(2)) was isolated after workup procedure. A tricyclic skeleton of the binuclear complex was characterized by the X-ray crystallography.

引用

页码：1177 / 1180

页数：4

共 5 条

[1] Preparation of carbonyltungsten(0) complexes of 2-chloro-3,3-diphenyl-1-(2,4,6-tri-tert-butylphenyl)-1,3-diphosphapropene
Ito, S
Yoshifuji, M
CHEMICAL COMMUNICATIONS, 2001, (13) : 1208 - 1209
[2] Structural and coordination properties of 3,3-diphenyl-1-(2,4,6-tri-tert-butylphenyl)-2-(trimethylsilyl)-1,3-diphosphapropene derivatives showing interesting conformational features
Ito, S
Nishide, K
Yoshifuji, M
ORGANOMETALLICS, 2006, 25 (06) : 1424 - 1430
[3] Preparation, structure, and some coordination properties of 2-chloro-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-t-butylphenyl)-1,3-diphosphapropene
Ito, S
Liang, HZ
Yoshifuji, M
CHEMICAL COMMUNICATIONS, 2003, (03) : 398 - 399
[4] Preparation, structure and coordination properties of 3,3-bis(diisopropylamino)-3-thioxo-1-(2,4,6-tri-tert-butylphenyl)1,3-diphosphapropene
Liang, HZ
Ito, S
Yoshifuji, M
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (17) : 3054 - 3058
[5] A NOVEL PRODUCT DERIVED FROM REACTION OF 3,3-DIMETHYL-4-METHYLTHIO-1-BUTYNE WITH "DICHLOROBIS(BENZONITRILE)-PALLADIUM - X-RAY CRYSTAL-STRUCTURE OF CHLORO(2,4-BIS-(1'1'-DIMETHYL-2'-(METHYLTHIO)ETHYL)-3-FURYL-C,S,S)-PALLADIUM(II)
MCGRINDLE, R
FERGUSON, G
ARSENAULT, GJ
MCALEES, AJ
PARVEZ, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 246 (01) : C19 - C22

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