New Organic Electrode Materials for Ultrafast Electrochemical Energy Storage

被引:74
|
作者
Zhao-Karger, Zhirong [1 ]
Gao, Ping [1 ]
Ebert, Thomas [1 ]
Klyatskaya, Svetlana [2 ]
Chen, Zhi [2 ]
Ruben, Mario [2 ,3 ]
Fichtner, Maximilian [1 ,2 ]
机构
[1] Helmholtz Inst Ulm, D-89081 Ulm, Germany
[2] Karlsruhe Inst Technol, Inst Nanotechnol, Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[3] Univ Strasbourg, CNRS, IPCMS, 23 Rue Loess,BP 43, F-67034 Strasbourg 2, France
关键词
electrochemical applications; electrochemical polymerization; organic electrodes; porphyrin-based electrode materials; PORPHYRIN; PERFORMANCE; FRAMEWORK; COMPLEXES;
D O I
10.1002/adma.201806599
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic materials are both environmentally and economically attractive as potential electrode candidates. This Research News reports on a new class of stable and electrically conductive organic electrodes based on metal porphyrins with functional groups that are capable of electrochemical polymerization, rendering the materials promising for electrochemical applications. Their structural flexibility and the unique highly conjugated macrocyclic structure allows the produced organic electrodes to act as both cathode and anode materials giving access to fast charging as well as high cycling stability. The extreme thermal and chemical stability of the porphyrin-based organic electrodes and their chemical versatility suggest an important role for these molecular systems in the further development of novel electrochemical energy storage applications.
引用
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页数:7
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