Characterization of sulfonated poly(styrene-divinylbenzene) and poly(divinylbenzene) and its application as catalysts in esterification reaction

被引：39
|
作者：
Coutinho, Fernanda M. B. [1 ]
Rezende, Simone M.
Soares, Bluma G.
机构：
[1] UERJ, Inst Quim, Dept Proc Quim, BR-20559900 Rio De Janeiro, Brazil
[2] UFRJ, Inst Macromol Prof Eloisa Mano, BR-21945970 Rio De Janeiro, Brazil
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 102卷 / 04期
关键词：
sulfonated poly(styrene-divinylbenzene); sulfonated poly(divinylbenzene); catalyst activity; morphology characterization; sulfonic groups distribution;
D O I：
10.1002/app.24046
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polymeric supports based on divinylbenzene (DVB) were prepared by aqueous suspension polymerization in presence or absence of styrene (S), using toluene and n-heptane as diluents of the monomers. Poly(S-DVB) and poly(DVB) were sultonated with sulfuric acid in presence of 1,2-dichloroethane. The influence of the morphological structure of the supports and as a consequence of the catalyst on the esterification reaction of acetic acid with n-butanol was evaluated. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码：3616 / 3627
页数：12
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