Preparation of Triangular Silver Nanoparticles Using Polyvinyl pyrrolidone with Different Concentration

被引:1
|
作者
Li, Kai [1 ]
Fu, Rao [1 ,2 ]
Gao, Qing-ran [1 ]
Tang, Ai-wei [3 ]
Wang, Ying-feng [1 ]
机构
[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
[3] Beijing Jiaotong Univ, Dept Chem, Beijing 100044, Peoples R China
关键词
Triangular silver nanoparticles (Ag NPs); Spherical Ag NPs; PVP; Ostwald ripening; NANOPRISMS; NANOSPHERES;
D O I
10.4028/www.scientific.net/AMR.873.206
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper continues our previous work on preparation of triangular silver nanoparticles. The method proceeds with reaction of silver nitrate with hydrazine hydrate in the presence of polyvinyl pyrrolidone in aqueous solution. Effects of the concentration of PVP on the morphologies of Ag NPs were systematically investigated. The obtained Ag NPs were characterized by transmission electron microscopy and UV-visible spectrophotometer. The results showed that, triangular Ag NPs with edge lengths in the range of 50-200 nm were obtained using PVP as protective agent with lower concentration. As the concentration of PVP increased, spherical Ag NPs with their sizes about 6.2 nm were prepared and triangular Ag NPs were not obtained. The formation mechanism of triangular Ag NPs has been studied. Ostwald ripening is the driving force on the conversion of spherical Ag NPs to triangular Ag NPs in the presence of PVP.
引用
收藏
页码:206 / +
页数:3
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