An asymmetric supercapacitor with good electrochemical performances based on Ni(OH)2/AC/CNT and AC

被引:72
|
作者
Sui, Leping [1 ,2 ]
Tang, Shuihua [1 ,2 ]
Chen, Yongdong [1 ,3 ]
Dai, Zhen [1 ,3 ]
Huangfu, Haixin [1 ,2 ]
Zhu, Zhentao [1 ,2 ]
Qin, Xiaolong [1 ,2 ]
Deng, Yuxiao [1 ,2 ]
Haarberg, Geir Martin [4 ]
机构
[1] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
[2] Southwest Petr Univ, Sch Mat Sci & Engn, Chengdu 610500, Peoples R China
[3] Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Peoples R China
[4] Norwegian Univ Sci & Technol, Dept Mat Sci & Engn, N-7491 Trondheim, Norway
关键词
Asymmetric supercapacitor; Energy storage; Ni(OH)(2)/AC/CNT composite; Electrode material; NANOPOROUS CARBON; NICKEL HYDROXIDE; ACTIVATED CARBON; NI FOAM; GRAPHENE; COMPOSITE; OXIDE; NANOCOMPOSITE; FABRICATION; ELECTRODES;
D O I
10.1016/j.electacta.2015.09.111
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ni(OH)(2)/AC/CNT composite has been prepared via a green rapid microwave assisted method in an ethylene glycol medium. Scanning electron microscopy images show that Ni(OH)(2) nanoparticles, activated carbon spheres and nanotubes constructed a three-dimensional (3-D) connected network, which lead to a high specific capacitance 1038 F g(-1) at current density of 1 A g(-1). Based on Ni(OH)(2)/AC/CNT composite as positive electrode material and activated carbon as negative electrode material, an asymmetric supercapacitor of AC//Ni(OH)(2)/AC/CNT was fabricated. The unit supercapacitor demonstrates excellent electrochemical performances using non-woven fabric as separator and 6 M KOH as electrolyte within 1.6 V operation window. The maximum specific capacitance of 82.1 F g(-1) is achieved at 0.5 A g(-1) and the energy density can reach up to 32.3 Wh kg(-1) at power density of 504.8 W kg(-1). Furthermore, 83.5% capacitance retention is obtained after 1000 charge-discharge cycles. These results indicate that the AC//Ni(OH)(2)/AC/CNT supercapacitor is promising to be applied in a practical device for energy storage devices. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1159 / 1165
页数:7
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