3,3′,5,5′-Tetranitrobiphenyl

被引：0
|
作者：
Hammond, N. [1 ]
Carvalho, P. [1 ]
Wu, Y. [1 ]
Avery, M. A. [1 ,2 ,3 ]
机构：
[1] Univ Mississippi, Dept Med Chem, University, MS 38677 USA
[2] Univ Mississippi, Sch Pharm, Pharmaceut Sci Res Inst, Natl Ctr Nat Prod Res, University, MS 38677 USA
[3] Univ Mississippi, Dept Chem & Biochem, University, MS 38677 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1107/S1600536809011088
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C(12)H(6)N(4)O(8), is a biphenyl system that was synthesized as a building block for a new series of antimalarial compounds. The aromatic rings are oriented at a dihedral angle of 45.5 (2)degrees, and intermolecular short O center dot center dot center dot O contacts form a chain along the b axis. The strength of the interactions involved in this chain cause one of the rings to be slightly distorted, with the torsion angle between the nitro groups being 23.4 (2)degrees, whereas, in the other ring, both nitro systems are parallel, forming an angle of 9.6 (2)degrees with the plane of the aromatic ring to which they are bound. Furthermore, the three ring C atoms around the ring-ring linkage belong to a plane inclined by 4.5 (1)degrees in relation to the plane containing the other three C atoms, i.e. (NO(2)-)C-C-C(NO(2)). This distortion of the ring causes uncommonly short intermolecular O center dot center dot center dot O [3.038 (2) angstrom] and O center dot center dot center dot C [3.000 (4) and 3.214 (1) angstrom] contacts.
引用
收藏
页码：O1052 / U2301
页数：10
相关论文
共 50 条
  • [1] 3,3′,5,5′-Tetramethylterphenyl
    Xu, JY
    Côté, AP
    Chen, BL
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O1697 - O1698
  • [2] THERMOLYSIS OF 3,3',5,5'-TETRAPHENYLDIPHENOQUINONE
    HAY, AS
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (01): : 218 - &
  • [3] [3,3]RUTHENOCENOPHANES AND [5,5]RUTHENOCENOPHANES
    KAMIYAMA, S
    KIMURA, T
    KASAHARA, A
    IZUMI, T
    SHIMIZU, I
    WATABE, H
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 385 - 386
  • [4] Crystal structures of 5,5 '-bis(hydroxymethyl)-3,3 '-biisoxazole and 4,4 ',5,5 '-tetrakis(hydroxymethyl)-3,3 '-biisoxazole
    Sausa, Rosario C.
    Wingard, Leah A.
    Guzman, Pablo E.
    Pesce-Rodriguez, Rose A.
    Sabatini, Jesse J.
    Lavalij, Peter Y.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 196 - +
  • [5] PHARMACOKINETICS OF 3,3',5,5'-TETRACHLOROBIPHENYL IN MALE RAT
    TUEY, DB
    MATTHEWS, HB
    [J]. DRUG METABOLISM AND DISPOSITION, 1977, 5 (05) : 444 - 450
  • [6] COMPARISON OF PARTICULATE 3,3',5,5'-TETRAMETHYLBENZIDINE AND 3,3'-DIAMINOBENZIDINE AS CHROMOGENIC SUBSTRATES FOR IMMUNOBLOT
    BRAND, JA
    TSANG, VCW
    ZHOU, W
    SHUKLA, SB
    [J]. BIOTECHNIQUES, 1990, 8 (01) : 58 - 60
  • [7] ELECTRODEPOSITION OF THE CATIONIC RADICAL SALT OF 3,3',5,5'-TETRAMETHYLBENZIDINE
    AWANO, H
    OHIGASHI, H
    [J]. SYNTHETIC METALS, 1989, 32 (03) : 389 - 394
  • [8] 3,3′,5,5′-Tetramethylbenzidine for the colorimetric determination of manganese in water
    Serrat, FB
    [J]. MIKROCHIMICA ACTA, 1998, 129 (1-2) : 77 - 80
  • [9] 3,3′,5,5′-Tetramethylbiphenyl-4,4′-dicarbonitrile
    Britton, Doyle
    de Silva, Saliya A.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O2252 - O2253
  • [10] 3,3′,5,5′-Tetramethylbenzidme for the colorimetric determination of manganese in water
    F. Bosch Serrat
    [J]. Microchimica Acta, 1998, 129 : 77 - 80
12345