Crystal structure of 2,2-(benzenesulphonyl)-1-(4-chlorobenzoyl) cyclopropane

被引:0
|
作者
Raj, SSS
Ponnuswamy, MN
Shanmugam, G
Krishnaiah, M
机构
[1] Univ Madras, Dept Crystallog & Biophys, Chennai 600025, India
[2] Sri Venkateswara Univ, Dept Phys, Tirupati 517502, Andhra Pradesh, India
关键词
X-ray structure; cyclopropane; benzenesulphonyl; chlorobenzoyl; electron transfer; conformation;
D O I
暂无
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound (C22H17O5S2Cl) crystallizes in the monoclinic space group P2(1)/c with cell constants a = 10.511(2), b = 15.452(1), c = 13.025(2) Angstrom, beta = 103.70(2)degrees, V = 2055.3(5)Angstrom(3), Z=4, D-cal=1.49Mgm(-3) and T=293K. The structure was solved by direct methods and refined by full-matrix least-squares procedure using 3876 reflections to a final R=0.0526 and wR=0.1787. One of the benzenesulphonyl group is trans and the other is cis to cyclopropane ring. The structure is stabilized by van der Waal's type of interactions.
引用
收藏
页码:1333 / 1337
页数:5
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