Addition of benzyne to Gd@C82

被引：32
|
作者：
Lu, X [1 ]
Xu, JX [1 ]
He, XR [1 ]
Shi, ZJ [1 ]
Gu, ZN [1 ]
机构：
[1] Peking Univ, Dept Chem, Beijing 100871, Peoples R China
来源：
CHEMISTRY OF MATERIALS | 2004年 / 16卷 / 06期
关键词：
D O I：
10.1021/cm0353207
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first [2+2] cycloadducts of endohedral metallofullerenes were successfully synthesized by the addition of benzyne to Gd@C82. Two monoadducts were isolated by HPLC and characterized by MALDI TOF MS and vis-NIR as well as CV and DPV. Such novel derivatives will have potential applications in electronics.
引用
收藏
页码：953 / 955
页数：3
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