Self-organization of cyclic selenaethers to yield columnar structures

被引：30

作者：

Werz, DB ^{[1
]}

Rausch, BJ ^{[1
]}

Gleiter, R ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 33期

关键词：

crownethers; selenium; self-organization; tubular structures;

D O I：

10.1016/S0040-4039(02)01188-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The previously published X-ray structures of five cyclic selenaethers (1-5) revealed columnar arrangements in the solid state. In most cases (1-4) the distances between the chalcogen centers of neighboring stacks are shorter than the sum of the van der Waals radii. This is the first time that rather flexible Saturated cyclic compounds were reported to form three-dimensional columnar Structures due to non-bonding chalcogen-chalcogen interactions in the solid state. (C) 20021 Elsevier Science Ltd. All rights reserved.

引用

页码：5767 / 5769

页数：3

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