Titanium and Ruthenium Phthalocyanines for NO2 Sensors: A Mini-Review

被引：36
|
作者：
Paoletti, Anna Maria [1 ]
Pennesi, Giovanna [1 ]
Rossi, Gentilina [1 ]
Generosi, Amanda [2 ]
Paci, Barbara [2 ]
Albertini, Valerio Rossi [2 ]
机构：
[1] CNR, Ist Struttura Mat, I-00016 Monterotondo, Italy
[2] CNR, Ist Struttura Mat, I-00133 Rome, Italy
来源：
SENSORS | 2009年 / 9卷 / 07期
关键词：
phthalocyanine; X-ray reflectivity; NO2; sensors; ELECTRICAL-CONDUCTIVITY PROPERTIES; X-RAY REFLECTIVITY; LANGMUIR-BLODGETT-FILMS; GAS-SENSING PROPERTIES; (RUPC)(2) THIN-FILMS; NITROGEN-DIOXIDE; OXIDATION-PRODUCTS; CRYSTAL-STRUCTURE; CHEMICAL SENSORS; BIS(PHTHALOCYANINATO)TITANIUM(IV);
D O I：
10.3390/s90705277
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
This review presents studies devoted to the description and comprehension of phenomena connected with the sensing behaviour towards NO2 of films of two phthalocyanines, titanium bis-phthalocyanine and ruthenium phthalocyanine. Spectroscopic, conductometric, and morphological features recorded during exposure to the gas are explained and the mechanisms of gas-molecule interaction are also elucidated. The review also shows how X-ray reflectivity can be a useful tool for monitoring morphological parameters such as thickness and roughness that are demonstrated to be sensitive variables for monitoring the exposure of thin films of sensor materials to NO2 gas.
引用
收藏
页码：5277 / 5297
页数：21
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