Raney Ni catalyzed azide-alkyne cycloaddition reaction

被引：39
|
作者：
Rao, H. Surya Prakash [1 ]
Chakibanda, Guravaiah [1 ]
机构：
[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India
来源：
RSC ADVANCES | 2014年 / 4卷 / 86期
关键词：
TERMINAL ALKYNES; CLICK CHEMISTRY; LIGAND; 1,2,3-TRIAZOLES; MECHANISM;
D O I：
10.1039/c4ra07057g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Raney Ni efficiently catalyzes acetylene azide cycloaddition reactions to form 1,2,3-triazoles. Unlike the CuSO4/sodium ascorbate reagent system, there is no need for a reducing agent under Raney Ni catalysis. Terminal acetylene selectivity, 1,4-regioselectivity and mild reaction conditions are prominent features of the method. Mechanistic probing revealed that the reaction does not go through nickel acetylides.
引用
收藏
页码：46040 / 46048
页数：9
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