Synthesis of fibrous TiO2 from layered protonic tetratitanate by a hydrothermal soft chemical process

被引：17
|
作者：
Jing, XZ [1 ]
Li, YX [1 ]
Yang, QB [1 ]
Yin, QR [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Cerams & Superfine, Shanghai 200050, Peoples R China
来源：
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2004年 / 110卷 / 01期
关键词：
titanium oxides; whisker; layered protonic tetratitanate; hydrothermal; phase transitions;
D O I：
10.1016/j.mseb.2004.01.018
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Fibrous TiO2 (anatase) was prepared by a hydrothermal soft chemical process using H(2)Ti(4)O(9)(.)0.25H(2)O as a template precursor. The influence of reaction time, temperature and precursor concentration on the phase formation, morphology and crystal-axis orientation were studied. The results have shown that fibrous anatase can be obtained at 220 degreesC for 24 h with the precursor concentrations in the range of 0.025-0.100 M, and that particles had diameters of 0.2-1 mum and lengths of 2-20 mum. The fibrous TiO2 anatase prepared by this method showed a high orientation along a-axis direction. X-ray diffractometer (XRD) and SEM analyses have indicated that in situ transformation mechanism dominated the entire hydrothermal process but dissolution-recrystallization also occurred on the surface of the particles. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：18 / 22
页数：5
相关论文
共 50 条
  • [1] Morphology control of TiO2 through hydrothermal synthesis method using protonic tetratitanate
    Wang, Jinshu
    Li, Hongyi
    Wang, Hong
    Huang, Kelin
    Sun, Guosong
    Yin, Shu
    Sato, Tsugio
    RESEARCH ON CHEMICAL INTERMEDIATES, 2011, 37 (2-5) : 165 - 175
  • [2] Morphology control of TiO2 through hydrothermal synthesis method using protonic tetratitanate
    Jinshu Wang
    Hongyi Li
    Hong Wang
    Kelin Huang
    Guosong Sun
    Shu Yin
    Tsugio Sato
    Research on Chemical Intermediates, 2011, 37 : 165 - 175
  • [3] THE SOFT CHEMICAL SYNTHESIS OF TIO2 (B) FROM LAYERED TITANATES
    FEIST, TP
    DAVIES, PK
    JOURNAL OF SOLID STATE CHEMISTRY, 1992, 101 (02) : 275 - 295
  • [4] Synthesis and photocatalytic properties of fibrous titania prepared from protonic layered tetratitanate precursor in supercritical alcohols
    Yin, S
    Sato, T
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (12) : 4526 - 4530
  • [5] Formation of nanotubes TiO2 from layered titanate particles by a soft chemical process
    Wei, MD
    Konishi, Y
    Zhou, HS
    Sugihara, H
    Arakawa, H
    SOLID STATE COMMUNICATIONS, 2005, 133 (08) : 493 - 497
  • [6] Synthesis of layered nanostructured TiO2 by hydrothermal method
    Tan, Zhenquan
    Sato, Kazuyoshi
    Ohara, Satoshi
    ADVANCED POWDER TECHNOLOGY, 2015, 26 (01) : 296 - 302
  • [7] Synthesis of lithiophorite with sandwich layered structure by hydrothermal soft chemical process
    Feng, Q
    Honbu, C
    Yanagisawa, K
    Yamasaki, N
    CHEMISTRY LETTERS, 1998, (08) : 757 - 758
  • [8] A soft chemical synthesis of TiO2 nanobelts
    Wang, Wenzhong
    Ao, Ling
    MATERIALS LETTERS, 2010, 64 (08) : 912 - 914
  • [9] Synthesis of lithium manganese oxides from layered manganese oxides by hydrothermal soft chemical process
    Feng, Q
    Higashimoto, Y
    Kajiyoshi, K
    Yanagisawa, K
    JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (03) : 269 - 271
  • [10] Nanocoral architecture of TiO2 by hydrothermal process: Synthesis and characterization
    Mali, Sawanta S.
    Shinde, Pravin S.
    Betty, C. A.
    Bhosale, Popatrao N.
    Lee, Won J.
    Patil, Pramod S.
    APPLIED SURFACE SCIENCE, 2011, 257 (23) : 9737 - 9746
12345