Iron(II) hydrides bearing a tetradentate PSNP ligand

被引：14

作者：

Liu, Jianguo ^{[1
,2
]}

Zhang, Ailing ^{[1
]}

Song, Heng ^{[1
]}

Tong, Qingxiao ^{[2
]}

Tung, Chen-Ho ^{[1
]}

Wang, Wenguang ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Shandong, Peoples R China

[2] Shantou Univ, Dept Chem, Shantou 515063, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2018年 / 29卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Iron(II) hydride; Iron catalysis; Tetradentate ligand; Hydroboration; Aldehydes; TRANSFER HYDROGENATION; ASYMMETRIC HYDROGENATION; ALKENE HYDROBORATION; COMPLEXES; CATALYSTS; KETONES; HYDROSILYLATION; OXIDATION; PINACOLBORANE; AMINES;

D O I：

10.1016/j.cclet.2017.09.059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of iron(II) hydrides based on a tetradentate PSNP ligand were synthesized and fully characterized. All the iron(II) complexes feature a folded PSNP ligand with cis reactive sites. The hydrido iron complex [2H(NCMe)](BF4) is capable of catalyzing aldehyde hydroboration by pinacolborane (HBpin) and with extremely high efficiency at room temperature. Aldehydes with various functional groups are compatible. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：949 / 953

页数：5

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