The chalcogeno-Baylis-Hillman reaction of ketones and α-dicarbonyl compounds

被引：19
|
作者：
Kataoka, T [1 ]
Kinoshita, H [1 ]
Kinoshita, S [1 ]
Iwamura, T [1 ]
机构：
[1] Gifu Pharmaceut Univ, Gifu 5028585, Japan
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 18期
关键词：
D O I：
10.1039/b207646m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1-[2-(Methylsulfanyl) phenyl] prop-2-en-1-one reacted with ketones, alpha-diketones, and alpha-keto esters in the presence of BF3.Et2O to give Morita-Baylis-Hillman adducts.
引用
收藏
页码：2043 / 2045
页数：3
相关论文
共 50 条
  • [1] α-keto esters as electrophiles for the Chalcogeno-Baylis-Hillman reaction
    Basavaiah, D
    Muthukumaran, K
    Sreenivasulu, B
    SYNLETT, 1999, (08) : 1249 - 1250
  • [2] Photoswitchable interlocked thiodiglycolamide as a cocatalyst of a chalcogeno-Baylis-Hillman reaction
    Martinez-Cuezva, Alberto
    Saura-Sanmartin, Adrian
    Nicolas-Garcia, Tomas
    Navarro, Cristian
    Orenes, Raul-Angel
    Alajarin, Mateo
    Berna, Jose
    CHEMICAL SCIENCE, 2017, 8 (05) : 3775 - 3780
  • [3] A new entry to enantioselective synthesis of α-methylene-β-hydroxy ketones by the chalcogeno-Baylis-Hillman reaction
    Iwama, T
    Tsujiyama, S
    Kinoshita, H
    Kanematsu, K
    Tsurukami, Y
    Iwamura, T
    Watanabe, S
    Kataoka, T
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1999, 47 (07) : 956 - 961
  • [4] Chalcogeno Morita-Baylis-Hillman reaction of 2-(methylchalcogeno)phenyl vinyl ketones with aldehydes, ketones, and α-dicarbonyl compounds
    Kinoshita, H
    Kinoshita, S
    Munechika, Y
    Iwamura, T
    Watanabe, S
    Kataoka, T
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (24) : 4852 - 4861
  • [5] The chalcogeno-Baylis-Hillman reaction: the first examples catalysed by chalcogenides in the presence of Lewis acids
    Kataoka, T
    Iwama, T
    Tsujiyama, S
    CHEMICAL COMMUNICATIONS, 1998, (02) : 197 - 198
  • [6] The enantioselective chalcogeno-Baylis-Hillman reaction using a chiral hydroxy chalcogenide-TiCl4 complex
    Kataoka, T
    Iwama, T
    Tsujiyama, S
    Kanematsu, K
    Iwamura, T
    Watanabe, S
    CHEMISTRY LETTERS, 1999, (03) : 257 - 258
  • [7] A convenient synthesis of α-halomethylene aldols or β-halo-α-(hydroxyalkyl)acrylates using the chalcogeno-Baylis-Hillman reaction
    Kataoka, Tadashi
    Kinoshita, Hironori
    Kinoshita, Sayaka
    Iwamura, Tatsunori
    Watanabe, Shin-Ichi
    Angewandte Chemie (International Edition in English), 2000, 39 (13): : 2358 - 2360
  • [8] A convenient synthesis of α-halomethylene aldols or β-halo-α-(hydroxyalkyl)acrylates using the chalcogeno-Baylis-Hillman reaction
    Kataoka, T
    Kinoshita, H
    Kinoshita, S
    Iwamura, T
    Watanabe, S
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (13) : 2358 - 2360
  • [9] The chalcogeno-Baylis-Hillman reaction of an α,β-unsaturated thioester:: A new approach to α-methylene-β-hydroxy carboxylic acid derivatives
    Kataoka, T
    Iwama, T
    Kinoshita, H
    Tsujiyama, S
    Tsurukami, Y
    Iwamura, T
    Watanabe, S
    SYNLETT, 1999, (02) : 197 - +
  • [10] The chalcogeno-Baylis-Hillman reaction: A new preparation of allylic alcohols from aldehydes and electron-deficient alkenes
    Kataoka, T
    Iwama, T
    Tsujiyama, S
    Iwamura, T
    Watanabe, S
    TETRAHEDRON, 1998, 54 (39) : 11813 - 11824
12345