Diazo compounds: Recent applications in synthetic organic chemistry and beyond

被引:36
|
作者
Wang, Jianbo [1 ,2 ,3 ]
机构
[1] Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China
[2] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
关键词
Diazo compounds; Carbene; Asymmetric catalysis; Polymerization; Chemical biology; N-H BONDS; HIGHLY ENANTIOSELECTIVE INSERTION; OLEFIN CYCLOPROPANATION; CARBENE INSERTION; YLIDES; TOSYLHYDRAZONES; POLYMERIZATION; DIAZOMETHANES; REARRANGEMENT; DIAZOACETATES;
D O I
10.1016/j.tetlet.2022.154135
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Diazo compounds, due to their diverse and rich chemical properties, have remained as one of the major domains in the organic chemistry research for long time. In the past two decades, the research activities related to diazo compounds have gained increased momentum. In addition to the synthetic organic chemistry, diazo compounds have also been explored in other fields such as polymer science and chemical biology. This Perspective will briefly highlight these achievements made in the past two decades. (C) 2022 Published by Elsevier Ltd.
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页数:7
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