Simulation of Orientated Catalyst Layer in PEMFC Using a Microstructure Lattice Model

被引:4
|
作者
Zhang Jie-Jing [1 ,2 ]
Wang Yu-Xin [2 ]
Zhang Jian-Feng [1 ]
Xu Li [2 ]
机构
[1] Jilin Agr Univ, Sch Life Sci, Jilin Prov Innovat Platform Straw Comprehens Util, Changchun 130118, Peoples R China
[2] Tianjin Univ, Sch Chem Engn & Technol, State Key Lab Chem Engn, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
Orientated electrode; Microstructure; Lattice model; Catalyst utilization; Pt/C particle configuration; DIRECT NUMERICAL-SIMULATION; MEMBRANE FUEL-CELLS; PEFC ELECTRODES; CATHODE; PERFORMANCE; RECONSTRUCTION; TRANSPORT; OPTIMIZATION;
D O I
10.3866/PKU.WHXB201510221
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The orientated cathode in a proton exchange membrane fuel cell was simulated and compared with a random cathode using a microstructure lattice model. The differences between catalyst utilization and electrode performance were studied. Transport and electrochemical reactions in the model catalyst layer were calculated. The orientated cathode performed better than the traditional random cathode and was explained by variations of the oxygen levels, the over potential and the reaction rate across the catalyst layer with cell current density. Additionally, we examined the electrode performance at different thicknesses. Unlike the traditional random cathode, a thinner orientated cathode performed better.
引用
收藏
页码:2316 / 2323
页数:8
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