An infrared study of hydrogen bond stability in benzoic acid-trans-1,2-bis(4-pyridyl)ethylene complexes in the solid state and the implications for the design of supramolecular polymers

被引：9
|
作者：
St Pourçain, CB [1 ]
机构：
[1] Aston Univ, Sch Engn & Appl Sci, Birmingham B4 7ET, W Midlands, England
来源：
JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 11期
关键词：
D O I：
10.1039/a905581i
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Derivatives of benzoic acid were complexed with trans-1,2-bis(4-pyridyl)ethylene. Infrared spectroscopy was used to confirm complexation and a correlation was found between the value of nu-C=O for the complex in the solid state and the pK(a) of the benzoic acid derivative. The stabilities of the hydrogen bonds in the complexes were investigated by temperature dependent infrared spectroscopy. It was found that all of the complexes behaved in a similar way, the hydrogen bonds remained intact until the melting point of the complex was reached. The implications for the design of supramolecular polymers are discussed.
引用
收藏
页码：2727 / 2730
页数：4
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